4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate

The title compound, C(18)H(16)ClN(3)O(4)S, is a Schiff base ligand in which the H atom of the hydr­oxy group has moved to the N atom of the imine group, resulting in a zwitterion. The structure is stabilized by an intra­molecular (N—H⋯O) and five inter­molecular (C—H⋯O, C—H⋯N and N—H⋯O) hydrogen bon...

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Detalles Bibliográficos
Autores principales: Shad, Hazoor A., Chohan, Zahid H., Tahir, M. Nawaz, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960758/
https://www.ncbi.nlm.nih.gov/pubmed/21201966
http://dx.doi.org/10.1107/S1600536808005321
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author Shad, Hazoor A.
Chohan, Zahid H.
Tahir, M. Nawaz
Khan, Islam Ullah
author_facet Shad, Hazoor A.
Chohan, Zahid H.
Tahir, M. Nawaz
Khan, Islam Ullah
author_sort Shad, Hazoor A.
collection PubMed
description The title compound, C(18)H(16)ClN(3)O(4)S, is a Schiff base ligand in which the H atom of the hydr­oxy group has moved to the N atom of the imine group, resulting in a zwitterion. The structure is stabilized by an intra­molecular (N—H⋯O) and five inter­molecular (C—H⋯O, C—H⋯N and N—H⋯O) hydrogen bonds. The mol­ecules are linked to each other by hydrogen bonds and form a three-dimensional polymeric network. In addition, the aromatic rings are also involved in π–π inter­actions [centroid–centroid distance between aromatic rings = 3.7525 (11) Å].
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spelling pubmed-29607582010-12-30 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate Shad, Hazoor A. Chohan, Zahid H. Tahir, M. Nawaz Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)ClN(3)O(4)S, is a Schiff base ligand in which the H atom of the hydr­oxy group has moved to the N atom of the imine group, resulting in a zwitterion. The structure is stabilized by an intra­molecular (N—H⋯O) and five inter­molecular (C—H⋯O, C—H⋯N and N—H⋯O) hydrogen bonds. The mol­ecules are linked to each other by hydrogen bonds and form a three-dimensional polymeric network. In addition, the aromatic rings are also involved in π–π inter­actions [centroid–centroid distance between aromatic rings = 3.7525 (11) Å]. International Union of Crystallography 2008-02-27 /pmc/articles/PMC2960758/ /pubmed/21201966 http://dx.doi.org/10.1107/S1600536808005321 Text en © Shad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shad, Hazoor A.
Chohan, Zahid H.
Tahir, M. Nawaz
Khan, Islam Ullah
4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title_full 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title_fullStr 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title_full_unstemmed 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title_short 4-Chloro-2-[(E)-({4-[N-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
title_sort 4-chloro-2-[(e)-({4-[n-(3,4-dimethyl­isoxazol-5-yl)sulfamo­yl]phen­yl}iminio)meth­yl]phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960758/
https://www.ncbi.nlm.nih.gov/pubmed/21201966
http://dx.doi.org/10.1107/S1600536808005321
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AT chohanzahidh 4chloro2e4n34dimethylisoxazol5ylsulfamoylphenyliminiomethylphenolate
AT tahirmnawaz 4chloro2e4n34dimethylisoxazol5ylsulfamoylphenyliminiomethylphenolate
AT khanislamullah 4chloro2e4n34dimethylisoxazol5ylsulfamoylphenyliminiomethylphenolate

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