[N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate

In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra­dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance...

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Detalles Bibliográficos
Autores principales: Yang, Li, Deng, Dong-Yan, Li, Mei, Zhou, Xiang-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960759/
https://www.ncbi.nlm.nih.gov/pubmed/21201840
http://dx.doi.org/10.1107/S1600536808002882
Descripción
Sumario:In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra­dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance of 1.83 Å. The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis..

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