[N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate

In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra­dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Li, Deng, Dong-Yan, Li, Mei, Zhou, Xiang-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960759/
https://www.ncbi.nlm.nih.gov/pubmed/21201840
http://dx.doi.org/10.1107/S1600536808002882
_version_ 1782188817897226240
author Yang, Li
Deng, Dong-Yan
Li, Mei
Zhou, Xiang-Ge
author_facet Yang, Li
Deng, Dong-Yan
Li, Mei
Zhou, Xiang-Ge
author_sort Yang, Li
collection PubMed
description In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra­dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance of 1.83 Å. The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis..
format Text
id pubmed-2960759
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29607592010-12-30 [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate Yang, Li Deng, Dong-Yan Li, Mei Zhou, Xiang-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra­dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni—N(pyridine) distance of 1.94 Å and an average Ni—N(amide) distance of 1.83 Å. The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis.. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960759/ /pubmed/21201840 http://dx.doi.org/10.1107/S1600536808002882 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yang, Li
Deng, Dong-Yan
Li, Mei
Zhou, Xiang-Ge
[N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title_full [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title_fullStr [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title_full_unstemmed [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title_short [N,N′-(1,2-Diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate
title_sort [n,n′-(1,2-diphenyl­ethane-1,2-di­yl)bis­(pyridine-2-carboxamidato)]nickel(ii) diethyl ether hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960759/
https://www.ncbi.nlm.nih.gov/pubmed/21201840
http://dx.doi.org/10.1107/S1600536808002882
work_keys_str_mv AT yangli nn12diphenylethane12diylbispyridine2carboxamidatonickeliidiethyletherhemisolvate
AT dengdongyan nn12diphenylethane12diylbispyridine2carboxamidatonickeliidiethyletherhemisolvate
AT limei nn12diphenylethane12diylbispyridine2carboxamidatonickeliidiethyletherhemisolvate
AT zhouxiangge nn12diphenylethane12diylbispyridine2carboxamidatonickeliidiethyletherhemisolvate

Ejemplares similares