trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate

The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d (6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris­(hydroxy­meth­yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo...

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Detalles Bibliográficos
Autores principales: Lorenzini, Fabio, Patrick, Brian O., James, Brian R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960764/
https://www.ncbi.nlm.nih.gov/pubmed/21201856
http://dx.doi.org/10.1107/S1600536808003528
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author Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
author_facet Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
author_sort Lorenzini, Fabio
collection PubMed
description The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d (6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris­(hydroxy­meth­yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo­octa­diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol­ecules and the acetone mol­ecules are linked into a chain along the a axis by inter­molecular C—H⋯Cl and C—H⋯O hydrogen bonds.
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spelling pubmed-29607642010-12-30 trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate Lorenzini, Fabio Patrick, Brian O. James, Brian R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d (6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris­(hydroxy­meth­yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo­octa­diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol­ecules and the acetone mol­ecules are linked into a chain along the a axis by inter­molecular C—H⋯Cl and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-02-08 /pmc/articles/PMC2960764/ /pubmed/21201856 http://dx.doi.org/10.1107/S1600536808003528 Text en © Lorenzini et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lorenzini, Fabio
Patrick, Brian O.
James, Brian R.
trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title_full trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title_fullStr trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title_full_unstemmed trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title_short trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate
title_sort trans-carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(i) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960764/
https://www.ncbi.nlm.nih.gov/pubmed/21201856
http://dx.doi.org/10.1107/S1600536808003528
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AT jamesbrianr transcarbonylchloridobistriptolylphosphinerhodiumiacetonesolvate

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