catena-Poly[[silver(I)-μ-[N-(4-pyridyl­meth­yl)pyridine-4-carboxamide-κ(2) N:N′]] nitrate monohydrate]

The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag⋯O(nitrate) inter­actions [2.794 (6) and 2.867 (5) Å] are regarded as bonds, the...

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Detalles Bibliográficos
Autores principales: Ma, Yu-Tao, Sun, Bai-Wang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960773/
https://www.ncbi.nlm.nih.gov/pubmed/21201859
http://dx.doi.org/10.1107/S1600536807049082
Descripción
Sumario:The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag⋯O(nitrate) inter­actions [2.794 (6) and 2.867 (5) Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol­ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

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