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(E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate

In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are inter­connected by weak C—H⋯O inter­actions. The 4-methoxy­benzensulfonate anions are linked to wate...

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Autores principales: Kobkeatthawin, Thawanrat, Ruanwas, Pumsak, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960777/
https://www.ncbi.nlm.nih.gov/pubmed/21201973
http://dx.doi.org/10.1107/S1600536808005205
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author Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Kobkeatthawin, Thawanrat
collection PubMed
description In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are inter­connected by weak C—H⋯O inter­actions. The 4-methoxy­benzensulfonate anions are linked to water mol­ecules through O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by a C—H⋯π inter­action involving the methoxy­phenyl ring. The sulfonate anion is also involved in a weak intra­molecular C—H⋯O inter­action which generates an S(5) ring motif.
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spelling pubmed-29607772010-12-30 (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are inter­connected by weak C—H⋯O inter­actions. The 4-methoxy­benzensulfonate anions are linked to water mol­ecules through O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by a C—H⋯π inter­action involving the methoxy­phenyl ring. The sulfonate anion is also involved in a weak intra­molecular C—H⋯O inter­action which generates an S(5) ring motif. International Union of Crystallography 2008-02-29 /pmc/articles/PMC2960777/ /pubmed/21201973 http://dx.doi.org/10.1107/S1600536808005205 Text en © Kobkeatthawin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
Fun, Hoong-Kun
(E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title_full (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title_fullStr (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title_full_unstemmed (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title_short (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
title_sort (e)-2-[4-(dimethyl­amino)styr­yl]-1-methyl­quinolinium 4-methoxy­benzene­sulfonate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960777/
https://www.ncbi.nlm.nih.gov/pubmed/21201973
http://dx.doi.org/10.1107/S1600536808005205
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