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(E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are interconnected by weak C—H⋯O interactions. The 4-methoxybenzensulfonate anions are linked to wate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960777/ https://www.ncbi.nlm.nih.gov/pubmed/21201973 http://dx.doi.org/10.1107/S1600536808005205 |
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author | Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Kobkeatthawin, Thawanrat |
collection | PubMed |
description | In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are interconnected by weak C—H⋯O interactions. The 4-methoxybenzensulfonate anions are linked to water molecules through O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by a C—H⋯π interaction involving the methoxyphenyl ring. The sulfonate anion is also involved in a weak intramolecular C—H⋯O interaction which generates an S(5) ring motif. |
format | Text |
id | pubmed-2960777 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607772010-12-30 (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(4)S(−)·H(2)O, the cation is nearly planar and exists in the E configuration. The cations and anions form individual chains along the b axis and are interconnected by weak C—H⋯O interactions. The 4-methoxybenzensulfonate anions are linked to water molecules through O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by a C—H⋯π interaction involving the methoxyphenyl ring. The sulfonate anion is also involved in a weak intramolecular C—H⋯O interaction which generates an S(5) ring motif. International Union of Crystallography 2008-02-29 /pmc/articles/PMC2960777/ /pubmed/21201973 http://dx.doi.org/10.1107/S1600536808005205 Text en © Kobkeatthawin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Fun, Hoong-Kun (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate |
title | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
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title_full | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
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title_fullStr | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
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title_full_unstemmed | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
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title_short | (E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate
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title_sort | (e)-2-[4-(dimethylamino)styryl]-1-methylquinolinium 4-methoxybenzenesulfonate monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960777/ https://www.ncbi.nlm.nih.gov/pubmed/21201973 http://dx.doi.org/10.1107/S1600536808005205 |
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