(2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate

The title compound, C(19)H(16)N(4)O(2)·0.425CH(4)O, crystallizes with two formula units per asymmetric unit. Researching its crystal structure constitutes part of a study of the nature of inter­actions between the N(+)—O(−) group and the vicinal NH group. The nitrone group and methanol solvent mol­e...

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Detalles Bibliográficos
Autores principales: Hodorowicz, Maciej, Stadnicka, Katarzyna, Trzewik, Bartosz, Zaleska, Barbara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960779/
https://www.ncbi.nlm.nih.gov/pubmed/21201937
http://dx.doi.org/10.1107/S1600536808003346
Descripción
Sumario:The title compound, C(19)H(16)N(4)O(2)·0.425CH(4)O, crystallizes with two formula units per asymmetric unit. Researching its crystal structure constitutes part of a study of the nature of inter­actions between the N(+)—O(−) group and the vicinal NH group. The nitrone group and methanol solvent mol­ecules are linked via four N—H⋯O and one O—H⋯O hydrogen bonds, with donor–acceptor distances of 2.603 (3)–2.730 (3) and 2.770 (3) Å, respectively. The crystal structure also involves two intermolecular N—H⋯N hydrogen bonds.

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