(2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate

The title compound, C(19)H(16)N(4)O(2)·0.425CH(4)O, crystallizes with two formula units per asymmetric unit. Researching its crystal structure constitutes part of a study of the nature of inter­actions between the N(+)—O(−) group and the vicinal NH group. The nitrone group and methanol solvent mol­e...

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Detalles Bibliográficos
Autores principales: Hodorowicz, Maciej, Stadnicka, Katarzyna, Trzewik, Bartosz, Zaleska, Barbara
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960779/
https://www.ncbi.nlm.nih.gov/pubmed/21201937
http://dx.doi.org/10.1107/S1600536808003346
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author Hodorowicz, Maciej
Stadnicka, Katarzyna
Trzewik, Bartosz
Zaleska, Barbara
author_facet Hodorowicz, Maciej
Stadnicka, Katarzyna
Trzewik, Bartosz
Zaleska, Barbara
author_sort Hodorowicz, Maciej
collection PubMed
description The title compound, C(19)H(16)N(4)O(2)·0.425CH(4)O, crystallizes with two formula units per asymmetric unit. Researching its crystal structure constitutes part of a study of the nature of inter­actions between the N(+)—O(−) group and the vicinal NH group. The nitrone group and methanol solvent mol­ecules are linked via four N—H⋯O and one O—H⋯O hydrogen bonds, with donor–acceptor distances of 2.603 (3)–2.730 (3) and 2.770 (3) Å, respectively. The crystal structure also involves two intermolecular N—H⋯N hydrogen bonds.
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spelling pubmed-29607792010-12-30 (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate Hodorowicz, Maciej Stadnicka, Katarzyna Trzewik, Bartosz Zaleska, Barbara Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(16)N(4)O(2)·0.425CH(4)O, crystallizes with two formula units per asymmetric unit. Researching its crystal structure constitutes part of a study of the nature of inter­actions between the N(+)—O(−) group and the vicinal NH group. The nitrone group and methanol solvent mol­ecules are linked via four N—H⋯O and one O—H⋯O hydrogen bonds, with donor–acceptor distances of 2.603 (3)–2.730 (3) and 2.770 (3) Å, respectively. The crystal structure also involves two intermolecular N—H⋯N hydrogen bonds. International Union of Crystallography 2008-02-15 /pmc/articles/PMC2960779/ /pubmed/21201937 http://dx.doi.org/10.1107/S1600536808003346 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Hodorowicz, Maciej
Stadnicka, Katarzyna
Trzewik, Bartosz
Zaleska, Barbara
(2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title_full (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title_fullStr (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title_full_unstemmed (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title_short (2Z)-2-Anilino-2-[oxido(phen­yl)iminio]-N-(2-pyrid­yl)acetamide methanol 0.425-solvate
title_sort (2z)-2-anilino-2-[oxido(phen­yl)iminio]-n-(2-pyrid­yl)acetamide methanol 0.425-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960779/
https://www.ncbi.nlm.nih.gov/pubmed/21201937
http://dx.doi.org/10.1107/S1600536808003346
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