4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate

In the Schiff base mol­ecule of the title compound, C(36)H(48)N(2)O(2)·C(3)H(6)O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. There are two intra­molecular O—H⋯N hydrogen b...

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Autores principales: Eltayeb, Naser Eltaher, Teoh, Siang Guan, Chantrapromma, Suchada, Fun, Hoong-Kun, Adnan, Rohana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960780/
https://www.ncbi.nlm.nih.gov/pubmed/21201917
http://dx.doi.org/10.1107/S1600536808003905
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author Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Adnan, Rohana
author_facet Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Adnan, Rohana
author_sort Eltayeb, Naser Eltaher
collection PubMed
description In the Schiff base mol­ecule of the title compound, C(36)H(48)N(2)O(2)·C(3)H(6)O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. There are two intra­molecular O—H⋯N hydrogen bonds involving the two hydr­oxy groups, which generate S(6) ring motifs. In the crystal structure, the Schiff base mol­ecules are linked into a chain along the a axis by C—H⋯π inter­actions. The acetone solvent mol­ecules are attached to the chain via C—H⋯O hydrogen bonds.
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spelling pubmed-29607802010-12-30 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Adnan, Rohana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the Schiff base mol­ecule of the title compound, C(36)H(48)N(2)O(2)·C(3)H(6)O, the central benzene ring makes dihedral angles of 46.64 (10) and 49.34 (10)° with the two outer benzene rings, and the two outer benzene rings form an angle of 39.13 (8)°. There are two intra­molecular O—H⋯N hydrogen bonds involving the two hydr­oxy groups, which generate S(6) ring motifs. In the crystal structure, the Schiff base mol­ecules are linked into a chain along the a axis by C—H⋯π inter­actions. The acetone solvent mol­ecules are attached to the chain via C—H⋯O hydrogen bonds. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960780/ /pubmed/21201917 http://dx.doi.org/10.1107/S1600536808003905 Text en © Eltayeb et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Adnan, Rohana
4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title_full 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title_fullStr 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title_full_unstemmed 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title_short 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
title_sort 4,4′,6,6′-tetra-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenol acetone solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960780/
https://www.ncbi.nlm.nih.gov/pubmed/21201917
http://dx.doi.org/10.1107/S1600536808003905
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