Cargando…
Dichloridobis[(S)-2-hydroxypropionamide-κ(2) O,O′]manganese(II)
In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lactamide molecules which act as bidentate ligands, giving rise to a highly distorted octahedral coordination geometry. The axial positions are occupied by one Cl atom and one...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960781/ https://www.ncbi.nlm.nih.gov/pubmed/21201860 http://dx.doi.org/10.1107/S1600536808004066 |
Sumario: | In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lactamide molecules which act as bidentate ligands, giving rise to a highly distorted octahedral coordination geometry. The axial positions are occupied by one Cl atom and one O (hydroxy) atom. The values of the cis bond angles at the Mn atom are in the range 72.33 (5)–100.17 (6)°. Of the two possible coordination modes (N,O- or O,O-bidentate) in metal complexes with lactamide or its derivatives described in the literature, the title compound exhibits the O,O-bidentate mode. In the crystal structure, monomeric manganese(II) complexes are linked by several N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional network. |
---|