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Dichloridobis[(S)-2-hydroxypropionamide-κ(2) O,O′]manganese(II)
In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lactamide molecules which act as bidentate ligands, giving rise to a highly distorted octahedral coordination geometry. The axial positions are occupied by one Cl atom and one...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960781/ https://www.ncbi.nlm.nih.gov/pubmed/21201860 http://dx.doi.org/10.1107/S1600536808004066 |
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author | Lemoine, Pascale Viossat, Bernard Brion, Jean Daniel Bekaert, Alain |
author_facet | Lemoine, Pascale Viossat, Bernard Brion, Jean Daniel Bekaert, Alain |
author_sort | Lemoine, Pascale |
collection | PubMed |
description | In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lactamide molecules which act as bidentate ligands, giving rise to a highly distorted octahedral coordination geometry. The axial positions are occupied by one Cl atom and one O (hydroxy) atom. The values of the cis bond angles at the Mn atom are in the range 72.33 (5)–100.17 (6)°. Of the two possible coordination modes (N,O- or O,O-bidentate) in metal complexes with lactamide or its derivatives described in the literature, the title compound exhibits the O,O-bidentate mode. In the crystal structure, monomeric manganese(II) complexes are linked by several N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional network. |
format | Text |
id | pubmed-2960781 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607812010-12-30 Dichloridobis[(S)-2-hydroxypropionamide-κ(2) O,O′]manganese(II) Lemoine, Pascale Viossat, Bernard Brion, Jean Daniel Bekaert, Alain Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lactamide molecules which act as bidentate ligands, giving rise to a highly distorted octahedral coordination geometry. The axial positions are occupied by one Cl atom and one O (hydroxy) atom. The values of the cis bond angles at the Mn atom are in the range 72.33 (5)–100.17 (6)°. Of the two possible coordination modes (N,O- or O,O-bidentate) in metal complexes with lactamide or its derivatives described in the literature, the title compound exhibits the O,O-bidentate mode. In the crystal structure, monomeric manganese(II) complexes are linked by several N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960781/ /pubmed/21201860 http://dx.doi.org/10.1107/S1600536808004066 Text en © Lemoine et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lemoine, Pascale Viossat, Bernard Brion, Jean Daniel Bekaert, Alain Dichloridobis[(S)-2-hydroxypropionamide-κ(2) O,O′]manganese(II) |
title | Dichloridobis[(S)-2-hydroxypropionamide-κ(2)
O,O′]manganese(II) |
title_full | Dichloridobis[(S)-2-hydroxypropionamide-κ(2)
O,O′]manganese(II) |
title_fullStr | Dichloridobis[(S)-2-hydroxypropionamide-κ(2)
O,O′]manganese(II) |
title_full_unstemmed | Dichloridobis[(S)-2-hydroxypropionamide-κ(2)
O,O′]manganese(II) |
title_short | Dichloridobis[(S)-2-hydroxypropionamide-κ(2)
O,O′]manganese(II) |
title_sort | dichloridobis[(s)-2-hydroxypropionamide-κ(2)
o,o′]manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960781/ https://www.ncbi.nlm.nih.gov/pubmed/21201860 http://dx.doi.org/10.1107/S1600536808004066 |
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