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Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)

In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lacta­mide mol­ecules which act as bidentate ligands, giving rise to a highly distorted octa­hedral coordination geometry. The axial positions are occupied by one Cl atom and one...

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Detalles Bibliográficos
Autores principales: Lemoine, Pascale, Viossat, Bernard, Brion, Jean Daniel, Bekaert, Alain
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960781/
https://www.ncbi.nlm.nih.gov/pubmed/21201860
http://dx.doi.org/10.1107/S1600536808004066
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author Lemoine, Pascale
Viossat, Bernard
Brion, Jean Daniel
Bekaert, Alain
author_facet Lemoine, Pascale
Viossat, Bernard
Brion, Jean Daniel
Bekaert, Alain
author_sort Lemoine, Pascale
collection PubMed
description In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lacta­mide mol­ecules which act as bidentate ligands, giving rise to a highly distorted octa­hedral coordination geometry. The axial positions are occupied by one Cl atom and one O (hydr­oxy) atom. The values of the cis bond angles at the Mn atom are in the range 72.33 (5)–100.17 (6)°. Of the two possible coordination modes (N,O- or O,O-bidentate) in metal complexes with lacta­mide or its derivatives described in the literature, the title compound exhibits the O,O-bidentate mode. In the crystal structure, monomeric manganese(II) complexes are linked by several N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-29607812010-12-30 Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II) Lemoine, Pascale Viossat, Bernard Brion, Jean Daniel Bekaert, Alain Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MnCl(2)(C(3)H(7)NO(2))(2)], the Mn(II) ion is bound to two Cl atoms and to four O atoms from two lacta­mide mol­ecules which act as bidentate ligands, giving rise to a highly distorted octa­hedral coordination geometry. The axial positions are occupied by one Cl atom and one O (hydr­oxy) atom. The values of the cis bond angles at the Mn atom are in the range 72.33 (5)–100.17 (6)°. Of the two possible coordination modes (N,O- or O,O-bidentate) in metal complexes with lacta­mide or its derivatives described in the literature, the title compound exhibits the O,O-bidentate mode. In the crystal structure, monomeric manganese(II) complexes are linked by several N—H⋯Cl, O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960781/ /pubmed/21201860 http://dx.doi.org/10.1107/S1600536808004066 Text en © Lemoine et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lemoine, Pascale
Viossat, Bernard
Brion, Jean Daniel
Bekaert, Alain
Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title_full Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title_fullStr Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title_full_unstemmed Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title_short Dichloridobis[(S)-2-hydroxy­propion­amide-κ(2) O,O′]manganese(II)
title_sort dichloridobis[(s)-2-hydroxy­propion­amide-κ(2) o,o′]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960781/
https://www.ncbi.nlm.nih.gov/pubmed/21201860
http://dx.doi.org/10.1107/S1600536808004066
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