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(1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate
The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960783/ https://www.ncbi.nlm.nih.gov/pubmed/21201953 http://dx.doi.org/10.1107/S1600536808004364 |
Sumario: | The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face π–π contacts, with an interplanar angle of 15.5 (2)° and a centroid–centroid distance of 4.73 (1) Å. One phenyl ring also forms a C—H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å. |
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