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(1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate

The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl­propane-1,3-dione using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter­molecular face-to-face...

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Detalles Bibliográficos
Autores principales: Fox, David J., Parris, Sean, Pedersen, Daniel Sejer, Warren, Stuart
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960783/
https://www.ncbi.nlm.nih.gov/pubmed/21201953
http://dx.doi.org/10.1107/S1600536808004364
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author Fox, David J.
Parris, Sean
Pedersen, Daniel Sejer
Warren, Stuart
author_facet Fox, David J.
Parris, Sean
Pedersen, Daniel Sejer
Warren, Stuart
author_sort Fox, David J.
collection PubMed
description The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl­propane-1,3-dione using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter­molecular face-to-face π–π contacts, with an inter­planar angle of 15.5 (2)° and a centroid–centroid distance of 4.73 (1) Å. One phenyl ring also forms a C—H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å.
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spelling pubmed-29607832010-12-30 (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate Fox, David J. Parris, Sean Pedersen, Daniel Sejer Warren, Stuart Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl­propane-1,3-dione using standard Sharpless asymmetric dihydroxy­lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter­molecular face-to-face π–π contacts, with an inter­planar angle of 15.5 (2)° and a centroid–centroid distance of 4.73 (1) Å. One phenyl ring also forms a C—H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å. International Union of Crystallography 2008-02-22 /pmc/articles/PMC2960783/ /pubmed/21201953 http://dx.doi.org/10.1107/S1600536808004364 Text en © Fox et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fox, David J.
Parris, Sean
Pedersen, Daniel Sejer
Warren, Stuart
(1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title_full (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title_fullStr (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title_full_unstemmed (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title_short (1R,2R)-4-Benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
title_sort (1r,2r)-4-benzoyl-2-benzo­yloxy-1-phenyl­butyl imidazole-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960783/
https://www.ncbi.nlm.nih.gov/pubmed/21201953
http://dx.doi.org/10.1107/S1600536808004364
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