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(1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate
The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960783/ https://www.ncbi.nlm.nih.gov/pubmed/21201953 http://dx.doi.org/10.1107/S1600536808004364 |
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author | Fox, David J. Parris, Sean Pedersen, Daniel Sejer Warren, Stuart |
author_facet | Fox, David J. Parris, Sean Pedersen, Daniel Sejer Warren, Stuart |
author_sort | Fox, David J. |
collection | PubMed |
description | The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face π–π contacts, with an interplanar angle of 15.5 (2)° and a centroid–centroid distance of 4.73 (1) Å. One phenyl ring also forms a C—H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å. |
format | Text |
id | pubmed-2960783 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29607832010-12-30 (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate Fox, David J. Parris, Sean Pedersen, Daniel Sejer Warren, Stuart Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenylpropane-1,3-dione using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form intermolecular face-to-face π–π contacts, with an interplanar angle of 15.5 (2)° and a centroid–centroid distance of 4.73 (1) Å. One phenyl ring also forms a C—H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å. International Union of Crystallography 2008-02-22 /pmc/articles/PMC2960783/ /pubmed/21201953 http://dx.doi.org/10.1107/S1600536808004364 Text en © Fox et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fox, David J. Parris, Sean Pedersen, Daniel Sejer Warren, Stuart (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title | (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title_full | (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title_fullStr | (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title_full_unstemmed | (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title_short | (1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
title_sort | (1r,2r)-4-benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960783/ https://www.ncbi.nlm.nih.gov/pubmed/21201953 http://dx.doi.org/10.1107/S1600536808004364 |
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