Cargando…
1-Ethyl-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide
In the title compound, C(10)H(11)NO(3)S, there is distorted tetrahedral geometry around the S atom. The heterocyclic thiazine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothia...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960787/ https://www.ncbi.nlm.nih.gov/pubmed/21201901 http://dx.doi.org/10.1107/S1600536808003504 |
Sumario: | In the title compound, C(10)H(11)NO(3)S, there is distorted tetrahedral geometry around the S atom. The heterocyclic thiazine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothiazine ring, excluding the S atom; the S atom and the ethyl group lie on opposite sides of the ring. The molecules are linked into dimers by intermolecular C—H⋯O hydrogen bonds involving benzene C—H and carbonyl O atoms, thus forming eight-membered rings. The dimers are linked into chains via interactions of a similar type. There is an intramolecular C—H⋯O hydrogen bond. |
---|