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1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide

In the title compound, C(10)H(11)NO(3)S, there is distorted tetra­hedral geometry around the S atom. The heterocyclic thia­zine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothia...

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Detalles Bibliográficos
Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Tahir, M. Nawaz, Siddiqui, Waseeq Ahmad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960787/
https://www.ncbi.nlm.nih.gov/pubmed/21201901
http://dx.doi.org/10.1107/S1600536808003504
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author Shafiq, Muhammad
Khan, Islam Ullah
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(10)H(11)NO(3)S, there is distorted tetra­hedral geometry around the S atom. The heterocyclic thia­zine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothia­zine ring, excluding the S atom; the S atom and the ethyl group lie on opposite sides of the ring. The mol­ecules are linked into dimers by inter­molecular C—H⋯O hydrogen bonds involving benzene C—H and carbonyl O atoms, thus forming eight-membered rings. The dimers are linked into chains via inter­actions of a similar type. There is an intra­molecular C—H⋯O hydrogen bond.
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spelling pubmed-29607872010-12-30 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide Shafiq, Muhammad Khan, Islam Ullah Tahir, M. Nawaz Siddiqui, Waseeq Ahmad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(11)NO(3)S, there is distorted tetra­hedral geometry around the S atom. The heterocyclic thia­zine ring adopts a half-chair conformation. The ethyl and sulfonyl groups form dihedral angles of 82.53 (13) and 88.91 (9)°, respectively, with the plane formed by the benzothia­zine ring, excluding the S atom; the S atom and the ethyl group lie on opposite sides of the ring. The mol­ecules are linked into dimers by inter­molecular C—H⋯O hydrogen bonds involving benzene C—H and carbonyl O atoms, thus forming eight-membered rings. The dimers are linked into chains via inter­actions of a similar type. There is an intra­molecular C—H⋯O hydrogen bond. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960787/ /pubmed/21201901 http://dx.doi.org/10.1107/S1600536808003504 Text en © Shafiq et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Tahir, M. Nawaz
Siddiqui, Waseeq Ahmad
1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title_full 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title_fullStr 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title_full_unstemmed 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title_short 1-Ethyl-1H-2,1-benzothia­zin-4(3H)-one 2,2-dioxide
title_sort 1-ethyl-1h-2,1-benzothia­zin-4(3h)-one 2,2-dioxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960787/
https://www.ncbi.nlm.nih.gov/pubmed/21201901
http://dx.doi.org/10.1107/S1600536808003504
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