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{2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)

In the title compound, [Zn(C(21)H(25)N(3)O(2))], the Zn(II) atom is five-coordinate from three N donor atoms and two O donor atoms of the dianion ligand in a distorted trigonal–bipyramidal arrangement. Three methyl­ene groups of the ligand are disordered over two orientations in a 0.555 (6):0.445 (6...

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Detalles Bibliográficos
Autores principales: Tai, Xi-Shi, Feng, Yi-Min, Zhang, Hua-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960793/
https://www.ncbi.nlm.nih.gov/pubmed/21201882
http://dx.doi.org/10.1107/S1600536808005060
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author Tai, Xi-Shi
Feng, Yi-Min
Zhang, Hua-Xiang
author_facet Tai, Xi-Shi
Feng, Yi-Min
Zhang, Hua-Xiang
author_sort Tai, Xi-Shi
collection PubMed
description In the title compound, [Zn(C(21)H(25)N(3)O(2))], the Zn(II) atom is five-coordinate from three N donor atoms and two O donor atoms of the dianion ligand in a distorted trigonal–bipyramidal arrangement. Three methyl­ene groups of the ligand are disordered over two orientations in a 0.555 (6):0.445 (6) ratio.
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spelling pubmed-29607932010-12-30 {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) Tai, Xi-Shi Feng, Yi-Min Zhang, Hua-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(21)H(25)N(3)O(2))], the Zn(II) atom is five-coordinate from three N donor atoms and two O donor atoms of the dianion ligand in a distorted trigonal–bipyramidal arrangement. Three methyl­ene groups of the ligand are disordered over two orientations in a 0.555 (6):0.445 (6) ratio. International Union of Crystallography 2008-02-29 /pmc/articles/PMC2960793/ /pubmed/21201882 http://dx.doi.org/10.1107/S1600536808005060 Text en © Tai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tai, Xi-Shi
Feng, Yi-Min
Zhang, Hua-Xiang
{2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title_full {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title_fullStr {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title_full_unstemmed {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title_short {2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)
title_sort {2,2′-[4-methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960793/
https://www.ncbi.nlm.nih.gov/pubmed/21201882
http://dx.doi.org/10.1107/S1600536808005060
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