Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid

The chirality of the title compound, C(19)H(26)O(2), is solely generated by the presence of the double bond in the cyclo­hexene ring. This compound was synthesized to study the inter­action of the two enanti­omers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. In...

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Detalles Bibliográficos
Autores principales: Xie, Songwen, O’Hearn, Caryn R., Robinson, Paul D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960795/
https://www.ncbi.nlm.nih.gov/pubmed/21201897
http://dx.doi.org/10.1107/S1600536808003309
Descripción
Sumario:The chirality of the title compound, C(19)H(26)O(2), is solely generated by the presence of the double bond in the cyclo­hexene ring. This compound was synthesized to study the inter­action of the two enanti­omers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. Inter­molecular O—H⋯O hydrogen bonds produce centrosymmetric R (2) (2)(8) rings which dimerize the two chiral enanti­omers through their carboxyl groups.

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