Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid

The chirality of the title compound, C(19)H(26)O(2), is solely generated by the presence of the double bond in the cyclo­hexene ring. This compound was synthesized to study the inter­action of the two enanti­omers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. In...

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Detalles Bibliográficos
Autores principales: Xie, Songwen, O’Hearn, Caryn R., Robinson, Paul D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960795/
https://www.ncbi.nlm.nih.gov/pubmed/21201897
http://dx.doi.org/10.1107/S1600536808003309
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author Xie, Songwen
O’Hearn, Caryn R.
Robinson, Paul D.
author_facet Xie, Songwen
O’Hearn, Caryn R.
Robinson, Paul D.
author_sort Xie, Songwen
collection PubMed
description The chirality of the title compound, C(19)H(26)O(2), is solely generated by the presence of the double bond in the cyclo­hexene ring. This compound was synthesized to study the inter­action of the two enanti­omers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. Inter­molecular O—H⋯O hydrogen bonds produce centrosymmetric R (2) (2)(8) rings which dimerize the two chiral enanti­omers through their carboxyl groups.
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spelling pubmed-29607952010-12-30 Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid Xie, Songwen O’Hearn, Caryn R. Robinson, Paul D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The chirality of the title compound, C(19)H(26)O(2), is solely generated by the presence of the double bond in the cyclo­hexene ring. This compound was synthesized to study the inter­action of the two enanti­omers in the solid state. The resultant racemate is made up of carboxylic acid RS dimers. Inter­molecular O—H⋯O hydrogen bonds produce centrosymmetric R (2) (2)(8) rings which dimerize the two chiral enanti­omers through their carboxyl groups. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960795/ /pubmed/21201897 http://dx.doi.org/10.1107/S1600536808003309 Text en © Xie et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xie, Songwen
O’Hearn, Caryn R.
Robinson, Paul D.
Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title_full Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title_fullStr Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title_full_unstemmed Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title_short Racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
title_sort racemic 4-(4-tert-butyl­phen­yl)-2,6-dimethyl­cyclo­hex-3-enecarboxylic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960795/
https://www.ncbi.nlm.nih.gov/pubmed/21201897
http://dx.doi.org/10.1107/S1600536808003309
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AT ohearncarynr racemic44tertbutylphenyl26dimethylcyclohex3enecarboxylicacid
AT robinsonpauld racemic44tertbutylphenyl26dimethylcyclohex3enecarboxylicacid

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