1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine

In the crystal structure of the title compound, C(22)H(17)N(3)O, the oxazine ring has a half-chair conformation. The dihedral angles between the best least-squares plane through the pyridine rings and the planar part (O–C–C–C–N) of the oxazine ring are 72.14 (6) and 35.44 (7)°, the smaller angle inv...

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Detalles Bibliográficos
Autores principales: Şen, Betül, Turgut, Zuhal, Pelit, Emel, Aygün, Muhittin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960797/
https://www.ncbi.nlm.nih.gov/pubmed/21201915
http://dx.doi.org/10.1107/S1600536808003887
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author Şen, Betül
Turgut, Zuhal
Pelit, Emel
Aygün, Muhittin
author_facet Şen, Betül
Turgut, Zuhal
Pelit, Emel
Aygün, Muhittin
author_sort Şen, Betül
collection PubMed
description In the crystal structure of the title compound, C(22)H(17)N(3)O, the oxazine ring has a half-chair conformation. The dihedral angles between the best least-squares plane through the pyridine rings and the planar part (O–C–C–C–N) of the oxazine ring are 72.14 (6) and 35.44 (7)°, the smaller angle involving the pyridine ring adjacent to the oxazine O atom. The mol­ecule has two stereogenic centers at the oxazine carbons, RS and SR. The crystal packing reveals that symmetry-related mol­ecules are linked by inter­molecular N—H⋯N hydrogen bonds to form chains parallel to the b axis.
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spelling pubmed-29607972010-12-30 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine Şen, Betül Turgut, Zuhal Pelit, Emel Aygün, Muhittin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(22)H(17)N(3)O, the oxazine ring has a half-chair conformation. The dihedral angles between the best least-squares plane through the pyridine rings and the planar part (O–C–C–C–N) of the oxazine ring are 72.14 (6) and 35.44 (7)°, the smaller angle involving the pyridine ring adjacent to the oxazine O atom. The mol­ecule has two stereogenic centers at the oxazine carbons, RS and SR. The crystal packing reveals that symmetry-related mol­ecules are linked by inter­molecular N—H⋯N hydrogen bonds to form chains parallel to the b axis. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960797/ /pubmed/21201915 http://dx.doi.org/10.1107/S1600536808003887 Text en © Şen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Şen, Betül
Turgut, Zuhal
Pelit, Emel
Aygün, Muhittin
1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title_full 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title_fullStr 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title_full_unstemmed 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title_short 1,3-Di-3-pyridyl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazine
title_sort 1,3-di-3-pyridyl-2,3-dihydro-1h-naphth[1,2-e][1,3]oxazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960797/
https://www.ncbi.nlm.nih.gov/pubmed/21201915
http://dx.doi.org/10.1107/S1600536808003887
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AT aygunmuhittin 13di3pyridyl23dihydro1hnaphth12e13oxazine

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