cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)

The asymmetric unit of the title compound, [RuCl(2)(C(13)H(9)N(3))(CO)(2)], consists of four crystallographically independent Ru(II) complexes. Each Ru(II) atom is in a distorted octa­hedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyrid­yl)-1,8-naphthyridin...

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Detalles Bibliográficos
Autores principales: Oyama, Dai, Hamada, Takashi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960803/
https://www.ncbi.nlm.nih.gov/pubmed/21201842
http://dx.doi.org/10.1107/S1600536808003188
Descripción
Sumario:The asymmetric unit of the title compound, [RuCl(2)(C(13)H(9)N(3))(CO)(2)], consists of four crystallographically independent Ru(II) complexes. Each Ru(II) atom is in a distorted octa­hedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyrid­yl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short inter­atomic distances (2.60–2.67 Å) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor–acceptor inter­action between the pynp and carbonyl ligands.

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