cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)

The asymmetric unit of the title compound, [RuCl(2)(C(13)H(9)N(3))(CO)(2)], consists of four crystallographically independent Ru(II) complexes. Each Ru(II) atom is in a distorted octa­hedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyrid­yl)-1,8-naphthyridin...

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Detalles Bibliográficos
Autores principales: Oyama, Dai, Hamada, Takashi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960803/
https://www.ncbi.nlm.nih.gov/pubmed/21201842
http://dx.doi.org/10.1107/S1600536808003188
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author Oyama, Dai
Hamada, Takashi
author_facet Oyama, Dai
Hamada, Takashi
author_sort Oyama, Dai
collection PubMed
description The asymmetric unit of the title compound, [RuCl(2)(C(13)H(9)N(3))(CO)(2)], consists of four crystallographically independent Ru(II) complexes. Each Ru(II) atom is in a distorted octa­hedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyrid­yl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short inter­atomic distances (2.60–2.67 Å) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor–acceptor inter­action between the pynp and carbonyl ligands.
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spelling pubmed-29608032010-12-30 cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II) Oyama, Dai Hamada, Takashi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RuCl(2)(C(13)H(9)N(3))(CO)(2)], consists of four crystallographically independent Ru(II) complexes. Each Ru(II) atom is in a distorted octa­hedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyrid­yl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short inter­atomic distances (2.60–2.67 Å) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor–acceptor inter­action between the pynp and carbonyl ligands. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960803/ /pubmed/21201842 http://dx.doi.org/10.1107/S1600536808003188 Text en © Oyama and Hamada 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oyama, Dai
Hamada, Takashi
cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title_full cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title_fullStr cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title_full_unstemmed cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title_short cis,trans-Dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κN (1),N (2)]ruthenium(II)
title_sort cis,trans-dicarbonyl­dichlorido[2-(2-pyrid­yl)-1,8-naphthyridine-κn (1),n (2)]ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960803/
https://www.ncbi.nlm.nih.gov/pubmed/21201842
http://dx.doi.org/10.1107/S1600536808003188
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AT hamadatakashi cistransdicarbonyldichlorido22pyridyl18naphthyridinekn1n2rutheniumii

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