N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea

In the title compound, C(19)H(17)ClN(4)O(2)S, the dihedral angle between the pyrazole and phenyl rings is 43.3 (3)°. The bridging unit between the pyrazole and methoxyphenyl rings is planar within 0.0169 Å and makes dihedral angles of 2.3 and 26.4°, respectively, with these two rings. This conformat...

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Detalles Bibliográficos
Autores principales: Du, Hai-tang, Du, Hai-jun, Lu, Ming, Sun, Li-li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960808/
https://www.ncbi.nlm.nih.gov/pubmed/21201945
http://dx.doi.org/10.1107/S1600536807068390
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author Du, Hai-tang
Du, Hai-jun
Lu, Ming
Sun, Li-li
author_facet Du, Hai-tang
Du, Hai-jun
Lu, Ming
Sun, Li-li
author_sort Du, Hai-tang
collection PubMed
description In the title compound, C(19)H(17)ClN(4)O(2)S, the dihedral angle between the pyrazole and phenyl rings is 43.3 (3)°. The bridging unit between the pyrazole and methoxyphenyl rings is planar within 0.0169 Å and makes dihedral angles of 2.3 and 26.4°, respectively, with these two rings. This conformation is influenced by intramolecular N—H⋯O and N—H⋯Cl hydrogen bonds. The crystal packing is stabilized by C—H⋯π inter­actions.
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spelling pubmed-29608082010-12-30 N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea Du, Hai-tang Du, Hai-jun Lu, Ming Sun, Li-li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(17)ClN(4)O(2)S, the dihedral angle between the pyrazole and phenyl rings is 43.3 (3)°. The bridging unit between the pyrazole and methoxyphenyl rings is planar within 0.0169 Å and makes dihedral angles of 2.3 and 26.4°, respectively, with these two rings. This conformation is influenced by intramolecular N—H⋯O and N—H⋯Cl hydrogen bonds. The crystal packing is stabilized by C—H⋯π inter­actions. International Union of Crystallography 2008-02-20 /pmc/articles/PMC2960808/ /pubmed/21201945 http://dx.doi.org/10.1107/S1600536807068390 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Du, Hai-tang
Du, Hai-jun
Lu, Ming
Sun, Li-li
N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title_full N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title_fullStr N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title_full_unstemmed N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title_short N-(5-Chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-N′-(2-methoxy­phen­yl)thio­urea
title_sort n-(5-chloro-3-methyl-1-phenyl­pyrazol-4-ylcarbon­yl)-n′-(2-methoxy­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960808/
https://www.ncbi.nlm.nih.gov/pubmed/21201945
http://dx.doi.org/10.1107/S1600536807068390
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