Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)

The asymmetric unit of the title compound, [Fe(2)(C(5)H(9)O(2))(4)(C(6)H(7)N)(2)], contains one unique Fe-atom site located close to a centre of symmetry which generates the mol­ecular dimer. The two Fe atoms are bridged by four carboxyl­ate groups and are each coordinated by a mol­ecule of 2-picoli...

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Detalles Bibliográficos
Autores principales: Overgaard, Jacob, Timco, Grigore A., Larsen, Finn K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960810/
https://www.ncbi.nlm.nih.gov/pubmed/21201879
http://dx.doi.org/10.1107/S1600536808005102
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author Overgaard, Jacob
Timco, Grigore A.
Larsen, Finn K.
author_facet Overgaard, Jacob
Timco, Grigore A.
Larsen, Finn K.
author_sort Overgaard, Jacob
collection PubMed
description The asymmetric unit of the title compound, [Fe(2)(C(5)H(9)O(2))(4)(C(6)H(7)N)(2)], contains one unique Fe-atom site located close to a centre of symmetry which generates the mol­ecular dimer. The two Fe atoms are bridged by four carboxyl­ate groups and are each coordinated by a mol­ecule of 2-picoline. Electron counting and the 18-electron rule suggest that a chemical single bond is likely to exist between the two Fe atoms, which are separated by a distance of 2.8576 (4) Å. This bond completes an approximately octa­hedral coordination environment around each Fe atom.
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spelling pubmed-29608102010-12-30 Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe) Overgaard, Jacob Timco, Grigore A. Larsen, Finn K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(2)(C(5)H(9)O(2))(4)(C(6)H(7)N)(2)], contains one unique Fe-atom site located close to a centre of symmetry which generates the mol­ecular dimer. The two Fe atoms are bridged by four carboxyl­ate groups and are each coordinated by a mol­ecule of 2-picoline. Electron counting and the 18-electron rule suggest that a chemical single bond is likely to exist between the two Fe atoms, which are separated by a distance of 2.8576 (4) Å. This bond completes an approximately octa­hedral coordination environment around each Fe atom. International Union of Crystallography 2008-02-27 /pmc/articles/PMC2960810/ /pubmed/21201879 http://dx.doi.org/10.1107/S1600536808005102 Text en © Overgaard et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Overgaard, Jacob
Timco, Grigore A.
Larsen, Finn K.
Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title_full Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title_fullStr Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title_full_unstemmed Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title_short Tetra­kis(μ-pivalato-κ(2) O:O′)bis­[(2-methyl­pyridine-κN)iron(II)](Fe—Fe)
title_sort tetra­kis(μ-pivalato-κ(2) o:o′)bis­[(2-methyl­pyridine-κn)iron(ii)](fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960810/
https://www.ncbi.nlm.nih.gov/pubmed/21201879
http://dx.doi.org/10.1107/S1600536808005102
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AT timcogrigorea tetrakismpivalatok2oobis2methylpyridineknironiifefe
AT larsenfinnk tetrakismpivalatok2oobis2methylpyridineknironiifefe

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