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A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II)
The title complex, [PtCl(2)(C(18)H(40)P(2))], contains a Pt(II) center in an approximately square-planar geometry [cis angle range = 88.09 (3)–91.39 (3)°; twist angle = 1.19 (5)°]. The Pt—P bond lengths of 2.2536 (8) and 2.2513 (8) Å and the Pt—Cl bond lengths of 2.3750 (8) and 2.3588 (8) Å are norm...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960814/ https://www.ncbi.nlm.nih.gov/pubmed/21201850 http://dx.doi.org/10.1107/S1600536808000603 |
| _version_ | 1782188831476285440 |
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| author | Gunay, Ahmet Brennessel, William W. Jones, William D. |
| author_facet | Gunay, Ahmet Brennessel, William W. Jones, William D. |
| author_sort | Gunay, Ahmet |
| collection | PubMed |
| description | The title complex, [PtCl(2)(C(18)H(40)P(2))], contains a Pt(II) center in an approximately square-planar geometry [cis angle range = 88.09 (3)–91.39 (3)°; twist angle = 1.19 (5)°]. The Pt—P bond lengths of 2.2536 (8) and 2.2513 (8) Å and the Pt—Cl bond lengths of 2.3750 (8) and 2.3588 (8) Å are normal. This crystal form is a polymorph of a structure reported previously [Harada, Kai, Yasuoka & Kasai (1976 ▶). Bull. Chem. Soc. Jpn, 49, 3472–3477]. |
| format | Text |
| id | pubmed-2960814 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29608142010-12-30 A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) Gunay, Ahmet Brennessel, William W. Jones, William D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [PtCl(2)(C(18)H(40)P(2))], contains a Pt(II) center in an approximately square-planar geometry [cis angle range = 88.09 (3)–91.39 (3)°; twist angle = 1.19 (5)°]. The Pt—P bond lengths of 2.2536 (8) and 2.2513 (8) Å and the Pt—Cl bond lengths of 2.3750 (8) and 2.3588 (8) Å are normal. This crystal form is a polymorph of a structure reported previously [Harada, Kai, Yasuoka & Kasai (1976 ▶). Bull. Chem. Soc. Jpn, 49, 3472–3477]. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960814/ /pubmed/21201850 http://dx.doi.org/10.1107/S1600536808000603 Text en © Gunay et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gunay, Ahmet Brennessel, William W. Jones, William D. A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title | A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title_full | A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title_fullStr | A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title_full_unstemmed | A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title_short | A second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(II) |
| title_sort | second polymorph of [1,2-bis(di-tert-butylphosphino)ethane]dichloridoplatinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960814/ https://www.ncbi.nlm.nih.gov/pubmed/21201850 http://dx.doi.org/10.1107/S1600536808000603 |
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