[2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)

In the title compound, [Ir(C(10)H(8)N(3))(C(11)H(8)N)(2)], the Ir center is octa­hedrally coordinated by the three chelating ligands, with two cyclo­metalated 2-pyridylphenyl ligands [Ir—N = 2.049 (5) and 2.030 (5) Å; Ir—C = 2.016 (6) and 2.012 (6) Å] and a bidentate 2-(phenyl­diazen­yl)pyrrolate li...

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Detalles Bibliográficos
Autores principales: Li, Wen-Ying, Mao, Li-Sheng, Lu, Long, He, Hong-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960816/
https://www.ncbi.nlm.nih.gov/pubmed/21201873
http://dx.doi.org/10.1107/S1600536808004443
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author Li, Wen-Ying
Mao, Li-Sheng
Lu, Long
He, Hong-Wu
author_facet Li, Wen-Ying
Mao, Li-Sheng
Lu, Long
He, Hong-Wu
author_sort Li, Wen-Ying
collection PubMed
description In the title compound, [Ir(C(10)H(8)N(3))(C(11)H(8)N)(2)], the Ir center is octa­hedrally coordinated by the three chelating ligands, with two cyclo­metalated 2-pyridylphenyl ligands [Ir—N = 2.049 (5) and 2.030 (5) Å; Ir—C = 2.016 (6) and 2.012 (6) Å] and a bidentate 2-(phenyl­diazen­yl)pyrrolate ligand [Ir—N = 2.204 (5) and 2.079 (5) Å]. The Ir—N(diazen­yl) bond is longer than the Ir—N(pyrrolate) bond. The structure is stabilized by aromatic π–π stacking, the shortest parallel distance between ring centroids being 3.426 (8) Å..
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spelling pubmed-29608162010-12-30 [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III) Li, Wen-Ying Mao, Li-Sheng Lu, Long He, Hong-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(10)H(8)N(3))(C(11)H(8)N)(2)], the Ir center is octa­hedrally coordinated by the three chelating ligands, with two cyclo­metalated 2-pyridylphenyl ligands [Ir—N = 2.049 (5) and 2.030 (5) Å; Ir—C = 2.016 (6) and 2.012 (6) Å] and a bidentate 2-(phenyl­diazen­yl)pyrrolate ligand [Ir—N = 2.204 (5) and 2.079 (5) Å]. The Ir—N(diazen­yl) bond is longer than the Ir—N(pyrrolate) bond. The structure is stabilized by aromatic π–π stacking, the shortest parallel distance between ring centroids being 3.426 (8) Å.. International Union of Crystallography 2008-02-20 /pmc/articles/PMC2960816/ /pubmed/21201873 http://dx.doi.org/10.1107/S1600536808004443 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wen-Ying
Mao, Li-Sheng
Lu, Long
He, Hong-Wu
[2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title_full [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title_fullStr [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title_full_unstemmed [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title_short [2-(Phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(III)
title_sort [2-(phenyl­diazen­yl)pyrrolato]bis(2-pyridylphen­yl)iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960816/
https://www.ncbi.nlm.nih.gov/pubmed/21201873
http://dx.doi.org/10.1107/S1600536808004443
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AT maolisheng 2phenyldiazenylpyrrolatobis2pyridylphenyliridiumiii
AT lulong 2phenyldiazenylpyrrolatobis2pyridylphenyliridiumiii
AT hehongwu 2phenyldiazenylpyrrolatobis2pyridylphenyliridiumiii

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