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(3-Aminophenyl)diphenylphosphine oxide–2-propanol (1/1)
The title compound, C(18)H(16)NOP·C(3)H(8)O, was synthesized by the reduction of (3-nitrophenyl)diphenylphosphine oxide in the presence of 2-propanol as recrystallization solvent. There are two molecules in the asymmetric unit. Each P atom is tetracoordinated by three C and one O atom from two p...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960822/ https://www.ncbi.nlm.nih.gov/pubmed/21201949 http://dx.doi.org/10.1107/S1600536808004674 |
Sumario: | The title compound, C(18)H(16)NOP·C(3)H(8)O, was synthesized by the reduction of (3-nitrophenyl)diphenylphosphine oxide in the presence of 2-propanol as recrystallization solvent. There are two molecules in the asymmetric unit. Each P atom is tetracoordinated by three C and one O atom from two phenyl fragments, one aniline group and one double-bonded O atom in a distorted tetrahedral geometry. C—H⋯π and N—H⋯π interactions are present. In the crystal structure, a wide range of non-covalent interactions consisting of hydrogen bonding [of the types of O—H⋯O, N—H⋯O and C—H⋯O, with D⋯A distances ranging from 2.680 (3) to 3.478 (3) Å] and π–π [centroid–centroid distance of 3.7720 (15) Å] stacking interactions connect the various components into a supramolecular structure. |
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