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1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate
The title compound, C(7)H(15)N(3)P(+)·BF(4) (−) or [PTA-Me][BF(4)], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetrafluoroborate anion; two F...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960824/ https://www.ncbi.nlm.nih.gov/pubmed/21201899 http://dx.doi.org/10.1107/S1600536808003401 |
| _version_ | 1782188834064171008 |
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| author | Smoleński, Piotr Kirillov, Alexander M. Guedes da Silva, M. Fátima C. Pombeiro, Armando J. L. |
| author_facet | Smoleński, Piotr Kirillov, Alexander M. Guedes da Silva, M. Fátima C. Pombeiro, Armando J. L. |
| author_sort | Smoleński, Piotr |
| collection | PubMed |
| description | The title compound, C(7)H(15)N(3)P(+)·BF(4) (−) or [PTA-Me][BF(4)], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetrafluoroborate anion; two F atoms are disordered equally over two sites. A network of weak intermolecular C—H⋯F hydrogen bonds results in a three-dimensional supramolecular assembly. |
| format | Text |
| id | pubmed-2960824 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29608242010-12-30 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate Smoleński, Piotr Kirillov, Alexander M. Guedes da Silva, M. Fátima C. Pombeiro, Armando J. L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(15)N(3)P(+)·BF(4) (−) or [PTA-Me][BF(4)], is the N-methylated derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetrafluoroborate anion; two F atoms are disordered equally over two sites. A network of weak intermolecular C—H⋯F hydrogen bonds results in a three-dimensional supramolecular assembly. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960824/ /pubmed/21201899 http://dx.doi.org/10.1107/S1600536808003401 Text en © Smoleński et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Smoleński, Piotr Kirillov, Alexander M. Guedes da Silva, M. Fátima C. Pombeiro, Armando J. L. 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title_full | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title_fullStr | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title_full_unstemmed | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title_short | 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| title_sort | 1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1(3,7)]decane tetrafluoroborate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960824/ https://www.ncbi.nlm.nih.gov/pubmed/21201899 http://dx.doi.org/10.1107/S1600536808003401 |
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