Diaqua­bis(4-formyl­benzoato-κO)zinc(II)

The Zn(II) atom in the title compound, [Zn(C(8)H(5)O(3))(2)(H(2)O)(2)], which lies on a twofold rotation axis, is coordinated by two monodentate carboxyl­ate groups and two water mol­ecules in a tetra­hedral geometry; the geometry is distorted towards octa­hedral owing to two long Zn⋯O(carbon­yl) co...

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Detalles Bibliográficos
Autores principales: Deng, Zhao-Peng, Gao, Shan, Huo, Li-Hua, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960827/
https://www.ncbi.nlm.nih.gov/pubmed/21201845
http://dx.doi.org/10.1107/S1600536808003152
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author Deng, Zhao-Peng
Gao, Shan
Huo, Li-Hua
Ng, Seik Weng
author_facet Deng, Zhao-Peng
Gao, Shan
Huo, Li-Hua
Ng, Seik Weng
author_sort Deng, Zhao-Peng
collection PubMed
description The Zn(II) atom in the title compound, [Zn(C(8)H(5)O(3))(2)(H(2)O)(2)], which lies on a twofold rotation axis, is coordinated by two monodentate carboxyl­ate groups and two water mol­ecules in a tetra­hedral geometry; the geometry is distorted towards octa­hedral owing to two long Zn⋯O(carbon­yl) contacts [2.512 (2) Å]. Hydrogen-bonding inter­actions give rise to a three-dimensional network. The formyl group is disordered approximately equally over two positions.
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spelling pubmed-29608272010-12-30 Diaqua­bis(4-formyl­benzoato-κO)zinc(II) Deng, Zhao-Peng Gao, Shan Huo, Li-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(8)H(5)O(3))(2)(H(2)O)(2)], which lies on a twofold rotation axis, is coordinated by two monodentate carboxyl­ate groups and two water mol­ecules in a tetra­hedral geometry; the geometry is distorted towards octa­hedral owing to two long Zn⋯O(carbon­yl) contacts [2.512 (2) Å]. Hydrogen-bonding inter­actions give rise to a three-dimensional network. The formyl group is disordered approximately equally over two positions. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960827/ /pubmed/21201845 http://dx.doi.org/10.1107/S1600536808003152 Text en © Deng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Zhao-Peng
Gao, Shan
Huo, Li-Hua
Ng, Seik Weng
Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title_full Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title_fullStr Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title_full_unstemmed Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title_short Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
title_sort diaqua­bis(4-formyl­benzoato-κo)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960827/
https://www.ncbi.nlm.nih.gov/pubmed/21201845
http://dx.doi.org/10.1107/S1600536808003152
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AT gaoshan diaquabis4formylbenzoatokozincii
AT huolihua diaquabis4formylbenzoatokozincii
AT ngseikweng diaquabis4formylbenzoatokozincii

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