μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate

The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa­hedral environment, whereas the Re(VII) atoms show the typical tetra­hedral coordination mode. The dihedral a...

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Detalles Bibliográficos
Autores principales: Ruth, Kai, Morawitz, Thorsten, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960830/
https://www.ncbi.nlm.nih.gov/pubmed/21201878
http://dx.doi.org/10.1107/S160053680800490X
Descripción
Sumario:The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa­hedral environment, whereas the Re(VII) atoms show the typical tetra­hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°.

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