μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate

The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa­hedral environment, whereas the Re(VII) atoms show the typical tetra­hedral coordination mode. The dihedral a...

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Detalles Bibliográficos
Autores principales: Ruth, Kai, Morawitz, Thorsten, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960830/
https://www.ncbi.nlm.nih.gov/pubmed/21201878
http://dx.doi.org/10.1107/S160053680800490X
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author Ruth, Kai
Morawitz, Thorsten
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Ruth, Kai
Morawitz, Thorsten
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Ruth, Kai
collection PubMed
description The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa­hedral environment, whereas the Re(VII) atoms show the typical tetra­hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°.
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spelling pubmed-29608302010-12-30 μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate Ruth, Kai Morawitz, Thorsten Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa­hedral environment, whereas the Re(VII) atoms show the typical tetra­hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°. International Union of Crystallography 2008-02-27 /pmc/articles/PMC2960830/ /pubmed/21201878 http://dx.doi.org/10.1107/S160053680800490X Text en © Ruth et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ruth, Kai
Morawitz, Thorsten
Lerner, Hans-Wolfram
Bolte, Michael
μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title_full μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title_fullStr μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title_full_unstemmed μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title_short μ-Hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(I)] perrhenate
title_sort μ-hydroxido-bis­[(2,2′-bipyridine)tricarbonyl­rhenium(i)] perrhenate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960830/
https://www.ncbi.nlm.nih.gov/pubmed/21201878
http://dx.doi.org/10.1107/S160053680800490X
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AT morawitzthorsten mhydroxidobis22bipyridinetricarbonylrheniumiperrhenate
AT lernerhanswolfram mhydroxidobis22bipyridinetricarbonylrheniumiperrhenate
AT boltemichael mhydroxidobis22bipyridinetricarbonylrheniumiperrhenate

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