Cargando…
catena-Poly[[bis[μ-2-(3-pyridyl)-1H-benzimidazole]-κ(2) N (2):N (3);κ(2) N (3):N (2)-disilver(I)]-μ-2,5-dicarboxybenzene-1,4-dicarboxylato-κ(2) O (2):O (5)]
The title coordination polymer, [Ag(2)(C(10)H(4)O(8))(C(12)H(9)N(3))(2)](n), was prepared by a hydrothermal method. The Ag(I) atom exists in a strongly distorted trigonal coordination environment. Two Ag(I) ions related by an inversion centre are coordinated by two 2-(3-pyridyl)benzimidazole ligan...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960835/ https://www.ncbi.nlm.nih.gov/pubmed/21201880 http://dx.doi.org/10.1107/S1600536808004984 |
Sumario: | The title coordination polymer, [Ag(2)(C(10)H(4)O(8))(C(12)H(9)N(3))(2)](n), was prepared by a hydrothermal method. The Ag(I) atom exists in a strongly distorted trigonal coordination environment. Two Ag(I) ions related by an inversion centre are coordinated by two 2-(3-pyridyl)benzimidazole ligands, forming a centrosymmetric cyclic dimer. The bridging bidentate 2,5-dicarboxybenzene-1,4-dicarboxylate ligand is also located on an inversion centre and connects the binuclear units, generating a one-dimensional polymer. The almost-planar conformation of this ligand allows it to form a strong intramolecular O—H⋯O hydrogen bond. Finally, intermolecular N—H⋯O hydrogen bonds aggregate the chains into a three-dimensional framework. |
---|