Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate

The asymmetric unit of the title compound, [Mn(C(2)H(3)O(2))(2)(C(18)H(20)N(4))]·6H(2)O, consists of a neutral Mn(II) complex with six solvent water mol­ecules. In the complex, the Mn(2+) ion is eight-coordinated in a distorted square-anti­prismatic environment by four N atoms from the tetra­dentate...

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Detalles Bibliográficos
Autores principales: Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960837/
https://www.ncbi.nlm.nih.gov/pubmed/21201849
http://dx.doi.org/10.1107/S160053680800353X
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author Hwang, In-Chul
Ha, Kwang
author_facet Hwang, In-Chul
Ha, Kwang
author_sort Hwang, In-Chul
collection PubMed
description The asymmetric unit of the title compound, [Mn(C(2)H(3)O(2))(2)(C(18)H(20)N(4))]·6H(2)O, consists of a neutral Mn(II) complex with six solvent water mol­ecules. In the complex, the Mn(2+) ion is eight-coordinated in a distorted square-anti­prismatic environment by four N atoms from the tetra­dentate ligand N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays inter­molecular O—H⋯O hydrogen-bond inter­actions to form various kinds of ring structures and cyclic water clusters.
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spelling pubmed-29608372010-12-30 Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(C(2)H(3)O(2))(2)(C(18)H(20)N(4))]·6H(2)O, consists of a neutral Mn(II) complex with six solvent water mol­ecules. In the complex, the Mn(2+) ion is eight-coordinated in a distorted square-anti­prismatic environment by four N atoms from the tetra­dentate ligand N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays inter­molecular O—H⋯O hydrogen-bond inter­actions to form various kinds of ring structures and cyclic water clusters. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960837/ /pubmed/21201849 http://dx.doi.org/10.1107/S160053680800353X Text en © Hwang and Ha 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hwang, In-Chul
Ha, Kwang
Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title_full Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title_fullStr Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title_full_unstemmed Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title_short Diacetato[N,N′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(II) hexa­hydrate
title_sort diacetato[n,n′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine]manganese(ii) hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960837/
https://www.ncbi.nlm.nih.gov/pubmed/21201849
http://dx.doi.org/10.1107/S160053680800353X
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