Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate

The title compound, [Zn(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, is a monomeric complex. It contains two 4-fluoro­benzoate and two nicotinamide ligands and one uncoordinated water mol­ecule. The 4-fluoro­benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The si...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Çaylak, Nagihan, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960841/
https://www.ncbi.nlm.nih.gov/pubmed/21201854
http://dx.doi.org/10.1107/S1600536808003747
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author Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title compound, [Zn(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, is a monomeric complex. It contains two 4-fluoro­benzoate and two nicotinamide ligands and one uncoordinated water mol­ecule. The 4-fluoro­benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the Zn(II) atom may be described as highly distorted octa­hedral, with the two nicotinamide ligands arranged cis. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure.
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spelling pubmed-29608412010-12-30 Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate Hökelek, Tuncer Çaylak, Nagihan Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, is a monomeric complex. It contains two 4-fluoro­benzoate and two nicotinamide ligands and one uncoordinated water mol­ecule. The 4-fluoro­benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the Zn(II) atom may be described as highly distorted octa­hedral, with the two nicotinamide ligands arranged cis. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960841/ /pubmed/21201854 http://dx.doi.org/10.1107/S1600536808003747 Text en © Hökelek et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title_full Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title_fullStr Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title_full_unstemmed Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title_short Bis(4-fluoro­benzoato-κ(2) O,O′)bis­(nicotinamide-κN (1))zinc(II) monohydrate
title_sort bis(4-fluoro­benzoato-κ(2) o,o′)bis­(nicotinamide-κn (1))zinc(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960841/
https://www.ncbi.nlm.nih.gov/pubmed/21201854
http://dx.doi.org/10.1107/S1600536808003747
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AT caylaknagihan bis4fluorobenzoatok2oobisnicotinamidekn1zinciimonohydrate
AT necefogluhacali bis4fluorobenzoatok2oobisnicotinamidekn1zinciimonohydrate

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