Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)

The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4−) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of...

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Detalles Bibliográficos
Autores principales: Schäffer, Susan J. Cline, Berg, Rolf W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960843/
https://www.ncbi.nlm.nih.gov/pubmed/21201837
http://dx.doi.org/10.1107/S1600536808003851
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author Schäffer, Susan J. Cline
Berg, Rolf W.
author_facet Schäffer, Susan J. Cline
Berg, Rolf W.
author_sort Schäffer, Susan J. Cline
collection PubMed
description The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4−) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.
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spelling pubmed-29608432010-12-30 Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI) Schäffer, Susan J. Cline Berg, Rolf W. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, K(4)[Mo(VI)O(2)(SO(4))(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [Mo(VI)O(2)(SO(4))(3)](4−) anions, with the Mo(VI) atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960843/ /pubmed/21201837 http://dx.doi.org/10.1107/S1600536808003851 Text en © Schäffer and Berg 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Schäffer, Susan J. Cline
Berg, Rolf W.
Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title_full Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title_fullStr Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title_full_unstemmed Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title_short Tetra­potassium cis-dioxido-trans-bis­(sulfato-κO)sulfato(κ(2) O,O′)molybdate(VI)
title_sort tetra­potassium cis-dioxido-trans-bis­(sulfato-κo)sulfato(κ(2) o,o′)molybdate(vi)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960843/
https://www.ncbi.nlm.nih.gov/pubmed/21201837
http://dx.doi.org/10.1107/S1600536808003851
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