Cargando…
Dichlorido(9-methyladenine-κN (7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate
In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyladenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monoden...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960857/ https://www.ncbi.nlm.nih.gov/pubmed/21201851 http://dx.doi.org/10.1107/S1600536808003760 |
Sumario: | In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyladenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of molecules, interacting through two N—H⋯N hydrogen bonds. An intramolecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH(2) group and a chlorido ligand. Further short intra- and intermolecular C—H⋯Cl contacts are observed. |
---|