Cargando…
Dichlorido(9-methyladenine-κN (7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate
In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyladenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monoden...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960857/ https://www.ncbi.nlm.nih.gov/pubmed/21201851 http://dx.doi.org/10.1107/S1600536808003760 |
_version_ | 1782188842248306688 |
---|---|
author | Bruhn, Clemens Küger, Thomas Steinborn, Dirk |
author_facet | Bruhn, Clemens Küger, Thomas Steinborn, Dirk |
author_sort | Bruhn, Clemens |
collection | PubMed |
description | In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyladenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of molecules, interacting through two N—H⋯N hydrogen bonds. An intramolecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH(2) group and a chlorido ligand. Further short intra- and intermolecular C—H⋯Cl contacts are observed. |
format | Text |
id | pubmed-2960857 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29608572010-12-30 Dichlorido(9-methyladenine-κN (7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate Bruhn, Clemens Küger, Thomas Steinborn, Dirk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyladenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyladenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of molecules, interacting through two N—H⋯N hydrogen bonds. An intramolecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH(2) group and a chlorido ligand. Further short intra- and intermolecular C—H⋯Cl contacts are observed. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960857/ /pubmed/21201851 http://dx.doi.org/10.1107/S1600536808003760 Text en © Bruhn et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bruhn, Clemens Küger, Thomas Steinborn, Dirk Dichlorido(9-methyladenine-κN (7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title | Dichlorido(9-methyladenine-κN
(7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title_full | Dichlorido(9-methyladenine-κN
(7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title_fullStr | Dichlorido(9-methyladenine-κN
(7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title_full_unstemmed | Dichlorido(9-methyladenine-κN
(7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title_short | Dichlorido(9-methyladenine-κN
(7))(η(5)-pentamethylcyclopentadienyl)iridium(III) dichloromethane solvate |
title_sort | dichlorido(9-methyladenine-κn
(7))(η(5)-pentamethylcyclopentadienyl)iridium(iii) dichloromethane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960857/ https://www.ncbi.nlm.nih.gov/pubmed/21201851 http://dx.doi.org/10.1107/S1600536808003760 |
work_keys_str_mv | AT bruhnclemens dichlorido9methyladeninekn7ē5pentamethylcyclopentadienyliridiumiiidichloromethanesolvate AT kugerthomas dichlorido9methyladeninekn7ē5pentamethylcyclopentadienyliridiumiiidichloromethanesolvate AT steinborndirk dichlorido9methyladeninekn7ē5pentamethylcyclopentadienyliridiumiiidichloromethanesolvate |