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Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate

In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyl­adenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyl­adenine ligand is coordinated in a monoden...

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Autores principales: Bruhn, Clemens, Küger, Thomas, Steinborn, Dirk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960857/
https://www.ncbi.nlm.nih.gov/pubmed/21201851
http://dx.doi.org/10.1107/S1600536808003760
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author Bruhn, Clemens
Küger, Thomas
Steinborn, Dirk
author_facet Bruhn, Clemens
Küger, Thomas
Steinborn, Dirk
author_sort Bruhn, Clemens
collection PubMed
description In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyl­adenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyl­adenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of mol­ecules, inter­acting through two N—H⋯N hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH(2) group and a chlorido ligand. Further short intra- and inter­molecular C—H⋯Cl contacts are observed.
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spelling pubmed-29608572010-12-30 Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate Bruhn, Clemens Küger, Thomas Steinborn, Dirk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(10)H(15))Cl(2)(C(6)H(7)N(5))]·CH(2)Cl(2) or [Ir(η(5)-C(5)Me(5))Cl(2)(9-MeAde-κN (7))]·CH(2)Cl(2) (9-MeAde = 9-methyl­adenine), the coordination geometry of the Ir(III) atom approximates to a three-legged piano stool. The 9-methyl­adenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of mol­ecules, inter­acting through two N—H⋯N hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH(2) group and a chlorido ligand. Further short intra- and inter­molecular C—H⋯Cl contacts are observed. International Union of Crystallography 2008-02-06 /pmc/articles/PMC2960857/ /pubmed/21201851 http://dx.doi.org/10.1107/S1600536808003760 Text en © Bruhn et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bruhn, Clemens
Küger, Thomas
Steinborn, Dirk
Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title_full Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title_fullStr Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title_full_unstemmed Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title_short Dichlorido(9-methyl­adenine-κN (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate
title_sort dichlorido(9-methyl­adenine-κn (7))(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(iii) dichloromethane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960857/
https://www.ncbi.nlm.nih.gov/pubmed/21201851
http://dx.doi.org/10.1107/S1600536808003760
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AT kugerthomas dichlorido9methyladeninekn7ē5pentamethylcyclopentadienyliridiumiiidichloromethanesolvate
AT steinborndirk dichlorido9methyladeninekn7ē5pentamethylcyclopentadienyliridiumiiidichloromethanesolvate