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Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))manganese(II)
The title complex, [Mn(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)], was obtained by hydrothermal synthesis. The Mn(II) atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen b...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960861/ https://www.ncbi.nlm.nih.gov/pubmed/21201864 http://dx.doi.org/10.1107/S160053680800411X |
| _version_ | 1782188843215093760 |
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| author | Zeng, Jian-Zhong Yi, Xiu-Guang Lin, Jun-Yue Ying, Shao-Ming Huang, Gan-Sheng |
| author_facet | Zeng, Jian-Zhong Yi, Xiu-Guang Lin, Jun-Yue Ying, Shao-Ming Huang, Gan-Sheng |
| author_sort | Zeng, Jian-Zhong |
| collection | PubMed |
| description | The title complex, [Mn(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)], was obtained by hydrothermal synthesis. The Mn(II) atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds to form a three-dimensional supramolecular structure. The title complex is isostructural with the corresponding cadmium(II) complex [Nie, Wen, Wu, Liu & Liu (2007 ▶). Acta Cryst. E63, m753–m755]. |
| format | Text |
| id | pubmed-2960861 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29608612010-12-30 Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))manganese(II) Zeng, Jian-Zhong Yi, Xiu-Guang Lin, Jun-Yue Ying, Shao-Ming Huang, Gan-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)], was obtained by hydrothermal synthesis. The Mn(II) atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds to form a three-dimensional supramolecular structure. The title complex is isostructural with the corresponding cadmium(II) complex [Nie, Wen, Wu, Liu & Liu (2007 ▶). Acta Cryst. E63, m753–m755]. International Union of Crystallography 2008-02-15 /pmc/articles/PMC2960861/ /pubmed/21201864 http://dx.doi.org/10.1107/S160053680800411X Text en © Zeng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zeng, Jian-Zhong Yi, Xiu-Guang Lin, Jun-Yue Ying, Shao-Ming Huang, Gan-Sheng Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))manganese(II) |
| title | Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))manganese(II) |
| title_full | Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))manganese(II) |
| title_fullStr | Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))manganese(II) |
| title_full_unstemmed | Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))manganese(II) |
| title_short | Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))manganese(II) |
| title_sort | diaquabis(5-carboxy-2-methyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960861/ https://www.ncbi.nlm.nih.gov/pubmed/21201864 http://dx.doi.org/10.1107/S160053680800411X |
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