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2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate
In the crystal structure of the title compound, C(14)H(14)F(3)O(7)P, the central chain, which connects the phosphate bicyclic system and the benzene ring, is made up of an approximately planar C—C(O)—O—C(H(2)) fragment and a C(H(2))—O—C(Ph) link; the mean planes make a dihedral angle of 75.9 (2)°. T...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960863/ https://www.ncbi.nlm.nih.gov/pubmed/21201921 http://dx.doi.org/10.1107/S1600536808003735 |
| _version_ | 1782188843700584448 |
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| author | Wang, Wei Wang, Wei-Dong Wang, Shao-Bin Shen, Yun-Li He, Hong-Wu |
| author_facet | Wang, Wei Wang, Wei-Dong Wang, Shao-Bin Shen, Yun-Li He, Hong-Wu |
| author_sort | Wang, Wei |
| collection | PubMed |
| description | In the crystal structure of the title compound, C(14)H(14)F(3)O(7)P, the central chain, which connects the phosphate bicyclic system and the benzene ring, is made up of an approximately planar C—C(O)—O—C(H(2)) fragment and a C(H(2))—O—C(Ph) link; the mean planes make a dihedral angle of 75.9 (2)°. The F atoms are disordered over two positions; the site occupancy factors are ca 0.6 and 0.4. |
| format | Text |
| id | pubmed-2960863 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29608632010-12-30 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate Wang, Wei Wang, Wei-Dong Wang, Shao-Bin Shen, Yun-Li He, Hong-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(14)F(3)O(7)P, the central chain, which connects the phosphate bicyclic system and the benzene ring, is made up of an approximately planar C—C(O)—O—C(H(2)) fragment and a C(H(2))—O—C(Ph) link; the mean planes make a dihedral angle of 75.9 (2)°. The F atoms are disordered over two positions; the site occupancy factors are ca 0.6 and 0.4. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960863/ /pubmed/21201921 http://dx.doi.org/10.1107/S1600536808003735 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Organic Papers Wang, Wei Wang, Wei-Dong Wang, Shao-Bin Shen, Yun-Li He, Hong-Wu 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title | 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title_full | 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title_fullStr | 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title_full_unstemmed | 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title_short | 2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| title_sort | 2-[3-(trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ(5)-phosphabicyclo[2.2.2]octane-4-carboxylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960863/ https://www.ncbi.nlm.nih.gov/pubmed/21201921 http://dx.doi.org/10.1107/S1600536808003735 |
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