Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)

The title compound, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Mn(II) atom lying on an inversion center. It contains two 4-chloro­benzoate and two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Çaylak, Nagihan, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960864/
https://www.ncbi.nlm.nih.gov/pubmed/21201885
http://dx.doi.org/10.1107/S1600536808005540
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author Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title compound, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Mn(II) atom lying on an inversion center. It contains two 4-chloro­benzoate and two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octa­hedral geometry is completed by two N atoms in the axial positions. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into an infinite chain.
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spelling pubmed-29608642010-12-30 Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II) Hökelek, Tuncer Çaylak, Nagihan Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], is a monomeric complex with the Mn(II) atom lying on an inversion center. It contains two 4-chloro­benzoate and two diethyl­nicotinamide ligands and two water mol­ecules, all of which are monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octa­hedral geometry is completed by two N atoms in the axial positions. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into an infinite chain. International Union of Crystallography 2008-02-29 /pmc/articles/PMC2960864/ /pubmed/21201885 http://dx.doi.org/10.1107/S1600536808005540 Text en © Hökelek et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Çaylak, Nagihan
Necefoğlu, Hacali
Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_full Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_fullStr Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_full_unstemmed Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_short Diaqua­bis(4-chloro­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))manganese(II)
title_sort diaqua­bis(4-chloro­benzoato-κo)bis­(n,n-diethyl­nicotinamide-κn (1))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960864/
https://www.ncbi.nlm.nih.gov/pubmed/21201885
http://dx.doi.org/10.1107/S1600536808005540
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AT caylaknagihan diaquabis4chlorobenzoatokobisnndiethylnicotinamidekn1manganeseii
AT necefogluhacali diaquabis4chlorobenzoatokobisnndiethylnicotinamidekn1manganeseii

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