{N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)

The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido­amine-supported zirconium–methyl complex that crystallized as a monomer with trigonal–bipyramidal geometry at zirconium, featuring a Zr—C bond of 2.2963 (16) Å.

Detalles Bibliográficos
Autores principales: MacMillan, Samantha N., Tanski, Joseph M., Waterman, Rory
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960865/
https://www.ncbi.nlm.nih.gov/pubmed/21201865
http://dx.doi.org/10.1107/S160053680800425X
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author MacMillan, Samantha N.
Tanski, Joseph M.
Waterman, Rory
author_facet MacMillan, Samantha N.
Tanski, Joseph M.
Waterman, Rory
author_sort MacMillan, Samantha N.
collection PubMed
description The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido­amine-supported zirconium–methyl complex that crystallized as a monomer with trigonal–bipyramidal geometry at zirconium, featuring a Zr—C bond of 2.2963 (16) Å.
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spelling pubmed-29608652010-12-30 {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV) MacMillan, Samantha N. Tanski, Joseph M. Waterman, Rory Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zr(CH(3))(C(15)H(39)N(4)Si(3))], is a unique example of a triamido­amine-supported zirconium–methyl complex that crystallized as a monomer with trigonal–bipyramidal geometry at zirconium, featuring a Zr—C bond of 2.2963 (16) Å. International Union of Crystallography 2008-02-15 /pmc/articles/PMC2960865/ /pubmed/21201865 http://dx.doi.org/10.1107/S160053680800425X Text en © MacMillan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
MacMillan, Samantha N.
Tanski, Joseph M.
Waterman, Rory
{N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title_full {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title_fullStr {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title_full_unstemmed {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title_short {N,N-Bis[2-(trimethyl­silylamino)eth­yl]-N′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) N}methyl­zirconium(IV)
title_sort {n,n-bis[2-(trimethyl­silylamino)eth­yl]-n′-(trimethyl­silyl)ethane-1,2-diamin­ato(3–)-κ(4) n}methyl­zirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960865/
https://www.ncbi.nlm.nih.gov/pubmed/21201865
http://dx.doi.org/10.1107/S160053680800425X
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