Dichloridobis(methyl­amine-κN)boron(III) chloride

The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(−) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(−), is the first crystallographically characterized di(alkyl­amine)–BCl(2) (+) salt. The B atom is tetra­hedrally coordinated by two Cl and two methyl­amine N atoms. In the crystal structure, the cations and anions in...

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Detalles Bibliográficos
Autores principales: Weinmann, Markus, Nuss, Jürgen, Jansen, Martin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960873/
https://www.ncbi.nlm.nih.gov/pubmed/21201922
http://dx.doi.org/10.1107/S1600536808003589
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author Weinmann, Markus
Nuss, Jürgen
Jansen, Martin
author_facet Weinmann, Markus
Nuss, Jürgen
Jansen, Martin
author_sort Weinmann, Markus
collection PubMed
description The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(−) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(−), is the first crystallographically characterized di(alkyl­amine)–BCl(2) (+) salt. The B atom is tetra­hedrally coordinated by two Cl and two methyl­amine N atoms. In the crystal structure, the cations and anions inter­act via N—H⋯Cl hydrogen bonds (mean H⋯Cl = 2.40 Å), resulting in a layered structure.
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spelling pubmed-29608732010-12-30 Dichloridobis(methyl­amine-κN)boron(III) chloride Weinmann, Markus Nuss, Jürgen Jansen, Martin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(−) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(−), is the first crystallographically characterized di(alkyl­amine)–BCl(2) (+) salt. The B atom is tetra­hedrally coordinated by two Cl and two methyl­amine N atoms. In the crystal structure, the cations and anions inter­act via N—H⋯Cl hydrogen bonds (mean H⋯Cl = 2.40 Å), resulting in a layered structure. International Union of Crystallography 2008-02-13 /pmc/articles/PMC2960873/ /pubmed/21201922 http://dx.doi.org/10.1107/S1600536808003589 Text en © Weinmann et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Weinmann, Markus
Nuss, Jürgen
Jansen, Martin
Dichloridobis(methyl­amine-κN)boron(III) chloride
title Dichloridobis(methyl­amine-κN)boron(III) chloride
title_full Dichloridobis(methyl­amine-κN)boron(III) chloride
title_fullStr Dichloridobis(methyl­amine-κN)boron(III) chloride
title_full_unstemmed Dichloridobis(methyl­amine-κN)boron(III) chloride
title_short Dichloridobis(methyl­amine-κN)boron(III) chloride
title_sort dichloridobis(methyl­amine-κn)boron(iii) chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960873/
https://www.ncbi.nlm.nih.gov/pubmed/21201922
http://dx.doi.org/10.1107/S1600536808003589
work_keys_str_mv AT weinmannmarkus dichloridobismethylamineknboroniiichloride
AT nussjurgen dichloridobismethylamineknboroniiichloride
AT jansenmartin dichloridobismethylamineknboroniiichloride

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