catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]

In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands. The monovalent anion, {[WS(4)Ag](−)}(n), forms a polymeric chain in a distorted linear c...

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Detalles Bibliográficos
Autores principales: Tang, Guodong, Zhang, Jinfang, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960880/
https://www.ncbi.nlm.nih.gov/pubmed/21201866
http://dx.doi.org/10.1107/S1600536808001256
Descripción
Sumario:In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands. The monovalent anion, {[WS(4)Ag](−)}(n), forms a polymeric chain in a distorted linear configuration with W—Ag—W and Ag—W—Ag angles of 163.81 (3) and 154.786 (12)°, respectively. Thirteen C and three N atoms are disordered equally over two positions. One C atom is disordered over two positions with site occupancy factors of 0.6 and 0.4.

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