catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]

In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands. The monovalent anion, {[WS(4)Ag](−)}(n), forms a polymeric chain in a distorted linear c...

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Detalles Bibliográficos
Autores principales: Tang, Guodong, Zhang, Jinfang, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960880/
https://www.ncbi.nlm.nih.gov/pubmed/21201866
http://dx.doi.org/10.1107/S1600536808001256
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author Tang, Guodong
Zhang, Jinfang
Zhang, Chi
author_facet Tang, Guodong
Zhang, Jinfang
Zhang, Chi
author_sort Tang, Guodong
collection PubMed
description In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands. The monovalent anion, {[WS(4)Ag](−)}(n), forms a polymeric chain in a distorted linear configuration with W—Ag—W and Ag—W—Ag angles of 163.81 (3) and 154.786 (12)°, respectively. Thirteen C and three N atoms are disordered equally over two positions. One C atom is disordered over two positions with site occupancy factors of 0.6 and 0.4.
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spelling pubmed-29608802010-12-30 catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]] Tang, Guodong Zhang, Jinfang Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands. The monovalent anion, {[WS(4)Ag](−)}(n), forms a polymeric chain in a distorted linear configuration with W—Ag—W and Ag—W—Ag angles of 163.81 (3) and 154.786 (12)°, respectively. Thirteen C and three N atoms are disordered equally over two positions. One C atom is disordered over two positions with site occupancy factors of 0.6 and 0.4. International Union of Crystallography 2008-02-15 /pmc/articles/PMC2960880/ /pubmed/21201866 http://dx.doi.org/10.1107/S1600536808001256 Text en © Tang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Guodong
Zhang, Jinfang
Zhang, Chi
catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title_full catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title_fullStr catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title_short catena-Poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κO)bis­(nitrato-κ(2) O,O′)neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]]
title_sort catena-poly[[tetra­kis(hexa­methyl­phos­pho­ramide-κo)bis­(nitrato-κ(2) o,o′)neodymium(iii)] [silver(i)-di-μ(2)-sulfido-tungsten(vi)-di-μ(2)-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960880/
https://www.ncbi.nlm.nih.gov/pubmed/21201866
http://dx.doi.org/10.1107/S1600536808001256
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AT zhangjinfang catenapolytetrakishexamethylphosphoramidekobisnitratok2ooneodymiumiiisilveridim2sulfidotungstenvidim2sulfido
AT zhangchi catenapolytetrakishexamethylphosphoramidekobisnitratok2ooneodymiumiiisilveridim2sulfidotungstenvidim2sulfido

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