μ(3)-Carbonato-κ(3) O:O′:O′′-tris­{(η(6)-ben­zene)[(R)-1-(1-amino­ethyl)naphthyl-κ(2) C (2),N]ruthenium(II)} hexa­fluorido­phosphate dichloro­methane solvate

The title compound, [Ru(3)(C(12)H(12)N)(3)(CO(3))(C(6)H(6))(3)]PF(6)·CH(2)Cl(2), was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C(12)H(12)N)(C(6)H(6))(C(2)H(3)N)]PF(6). The carbonate ligand bridges three half-sandwich cyclo­rut...

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Detalles Bibliográficos
Autores principales: Sortais, Jean-Baptiste, Brelot, Lydia, Pfeffer, Michel, Barloy, Laurent
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960882/
https://www.ncbi.nlm.nih.gov/pubmed/21201869
http://dx.doi.org/10.1107/S1600536808003978
Descripción
Sumario:The title compound, [Ru(3)(C(12)H(12)N)(3)(CO(3))(C(6)H(6))(3)]PF(6)·CH(2)Cl(2), was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C(12)H(12)N)(C(6)H(6))(C(2)H(3)N)]PF(6). The carbonate ligand bridges three half-sandwich cyclo­ruthenated fragments, each of them exhibiting a pseudo-tetra­hedral geometry. The configuration of the Ru atoms is S. The naphthyl groups of the enanti­opure cyclo­ruthenated benzylic amine ligands point in the same direction, adopting a propeller shape.

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