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μ(3)-Carbonato-κ(3) O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2) C (2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate
The title compound, [Ru(3)(C(12)H(12)N)(3)(CO(3))(C(6)H(6))(3)]PF(6)·CH(2)Cl(2), was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C(12)H(12)N)(C(6)H(6))(C(2)H(3)N)]PF(6). The carbonate ligand bridges three half-sandwich cyclorut...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960882/ https://www.ncbi.nlm.nih.gov/pubmed/21201869 http://dx.doi.org/10.1107/S1600536808003978 |
| _version_ | 1782188848358359040 |
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| author | Sortais, Jean-Baptiste Brelot, Lydia Pfeffer, Michel Barloy, Laurent |
| author_facet | Sortais, Jean-Baptiste Brelot, Lydia Pfeffer, Michel Barloy, Laurent |
| author_sort | Sortais, Jean-Baptiste |
| collection | PubMed |
| description | The title compound, [Ru(3)(C(12)H(12)N)(3)(CO(3))(C(6)H(6))(3)]PF(6)·CH(2)Cl(2), was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C(12)H(12)N)(C(6)H(6))(C(2)H(3)N)]PF(6). The carbonate ligand bridges three half-sandwich cycloruthenated fragments, each of them exhibiting a pseudo-tetrahedral geometry. The configuration of the Ru atoms is S. The naphthyl groups of the enantiopure cycloruthenated benzylic amine ligands point in the same direction, adopting a propeller shape. |
| format | Text |
| id | pubmed-2960882 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29608822010-12-30 μ(3)-Carbonato-κ(3) O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2) C (2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate Sortais, Jean-Baptiste Brelot, Lydia Pfeffer, Michel Barloy, Laurent Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(3)(C(12)H(12)N)(3)(CO(3))(C(6)H(6))(3)]PF(6)·CH(2)Cl(2), was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C(12)H(12)N)(C(6)H(6))(C(2)H(3)N)]PF(6). The carbonate ligand bridges three half-sandwich cycloruthenated fragments, each of them exhibiting a pseudo-tetrahedral geometry. The configuration of the Ru atoms is S. The naphthyl groups of the enantiopure cycloruthenated benzylic amine ligands point in the same direction, adopting a propeller shape. International Union of Crystallography 2008-02-15 /pmc/articles/PMC2960882/ /pubmed/21201869 http://dx.doi.org/10.1107/S1600536808003978 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Sortais, Jean-Baptiste Brelot, Lydia Pfeffer, Michel Barloy, Laurent μ(3)-Carbonato-κ(3) O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2) C (2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title | μ(3)-Carbonato-κ(3)
O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2)
C
(2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title_full | μ(3)-Carbonato-κ(3)
O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2)
C
(2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title_fullStr | μ(3)-Carbonato-κ(3)
O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2)
C
(2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title_full_unstemmed | μ(3)-Carbonato-κ(3)
O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2)
C
(2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title_short | μ(3)-Carbonato-κ(3)
O:O′:O′′-tris{(η(6)-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ(2)
C
(2),N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate |
| title_sort | μ(3)-carbonato-κ(3)
o:o′:o′′-tris{(η(6)-benzene)[(r)-1-(1-aminoethyl)naphthyl-κ(2)
c
(2),n]ruthenium(ii)} hexafluoridophosphate dichloromethane solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960882/ https://www.ncbi.nlm.nih.gov/pubmed/21201869 http://dx.doi.org/10.1107/S1600536808003978 |
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