4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane

The title compound [systematic name: 1(2)-amino-4(2)-(1-naphth­yl)-1,4(1,4)-dibenzenacyclo­hexa­phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo­phane and 1-naphthalene­boronic acid in the presence of 1,4-dioxane. It is a new cyclo­phane-derived compound which can be regarde...

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Detalles Bibliográficos
Autores principales: Sun, Junshan, Huo, Yanmin, Wu, Rentao, Li, Jikun, Ma, Yudao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960889/
https://www.ncbi.nlm.nih.gov/pubmed/21202048
http://dx.doi.org/10.1107/S1600536808005333
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author Sun, Junshan
Huo, Yanmin
Wu, Rentao
Li, Jikun
Ma, Yudao
author_facet Sun, Junshan
Huo, Yanmin
Wu, Rentao
Li, Jikun
Ma, Yudao
author_sort Sun, Junshan
collection PubMed
description The title compound [systematic name: 1(2)-amino-4(2)-(1-naphth­yl)-1,4(1,4)-dibenzenacyclo­hexa­phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo­phane and 1-naphthalene­boronic acid in the presence of 1,4-dioxane. It is a new cyclo­phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo­phane units are very slightly deformed from planarity as shallow boats.
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spelling pubmed-29608892010-12-30 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane Sun, Junshan Huo, Yanmin Wu, Rentao Li, Jikun Ma, Yudao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 1(2)-amino-4(2)-(1-naphth­yl)-1,4(1,4)-dibenzenacyclo­hexa­phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo­phane and 1-naphthalene­boronic acid in the presence of 1,4-dioxane. It is a new cyclo­phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo­phane units are very slightly deformed from planarity as shallow boats. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960889/ /pubmed/21202048 http://dx.doi.org/10.1107/S1600536808005333 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Sun, Junshan
Huo, Yanmin
Wu, Rentao
Li, Jikun
Ma, Yudao
4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title_full 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title_fullStr 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title_full_unstemmed 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title_short 4-Amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
title_sort 4-amino-13-(1-naphth­yl)-[2,2]paracyclo­phane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960889/
https://www.ncbi.nlm.nih.gov/pubmed/21202048
http://dx.doi.org/10.1107/S1600536808005333
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AT huoyanmin 4amino131naphthyl22paracyclophane
AT wurentao 4amino131naphthyl22paracyclophane
AT lijikun 4amino131naphthyl22paracyclophane
AT mayudao 4amino131naphthyl22paracyclophane

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