Cargando…
(2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate
In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetrahedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles s...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960891/ https://www.ncbi.nlm.nih.gov/pubmed/21201995 http://dx.doi.org/10.1107/S1600536808006260 |
Sumario: | In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetrahedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetrahedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring–ring C—C bond. The nitrate anion and the water and chloroform molecules of solvation are disordered. In the crystal structure, there are O(water)—H⋯O(nitrate), C—H⋯O(water) and C—H⋯O(nitrate) hydrogen bonds. |
---|