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(2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate
In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetrahedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles s...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960891/ https://www.ncbi.nlm.nih.gov/pubmed/21201995 http://dx.doi.org/10.1107/S1600536808006260 |
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author | Navarro, Maribel Corona, Oscar A. González, Teresa Capparelli, Mario V. |
author_facet | Navarro, Maribel Corona, Oscar A. González, Teresa Capparelli, Mario V. |
author_sort | Navarro, Maribel |
collection | PubMed |
description | In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetrahedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetrahedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring–ring C—C bond. The nitrate anion and the water and chloroform molecules of solvation are disordered. In the crystal structure, there are O(water)—H⋯O(nitrate), C—H⋯O(water) and C—H⋯O(nitrate) hydrogen bonds. |
format | Text |
id | pubmed-2960891 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29608912010-12-30 (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate Navarro, Maribel Corona, Oscar A. González, Teresa Capparelli, Mario V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetrahedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetrahedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring–ring C—C bond. The nitrate anion and the water and chloroform molecules of solvation are disordered. In the crystal structure, there are O(water)—H⋯O(nitrate), C—H⋯O(water) and C—H⋯O(nitrate) hydrogen bonds. International Union of Crystallography 2008-03-12 /pmc/articles/PMC2960891/ /pubmed/21201995 http://dx.doi.org/10.1107/S1600536808006260 Text en © Navarro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Navarro, Maribel Corona, Oscar A. González, Teresa Capparelli, Mario V. (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title | (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title_full | (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title_fullStr | (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title_full_unstemmed | (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title_short | (2,2′-Bipyridine)bis(triphenylphosphine)copper(I) nitrate chloroform solvate hemihydrate |
title_sort | (2,2′-bipyridine)bis(triphenylphosphine)copper(i) nitrate chloroform solvate hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960891/ https://www.ncbi.nlm.nih.gov/pubmed/21201995 http://dx.doi.org/10.1107/S1600536808006260 |
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