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(2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate

In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra­hedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles s...

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Detalles Bibliográficos
Autores principales: Navarro, Maribel, Corona, Oscar A., González, Teresa, Capparelli, Mario V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960891/
https://www.ncbi.nlm.nih.gov/pubmed/21201995
http://dx.doi.org/10.1107/S1600536808006260
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author Navarro, Maribel
Corona, Oscar A.
González, Teresa
Capparelli, Mario V.
author_facet Navarro, Maribel
Corona, Oscar A.
González, Teresa
Capparelli, Mario V.
author_sort Navarro, Maribel
collection PubMed
description In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra­hedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra­hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring–ring C—C bond. The nitrate anion and the water and chloro­form mol­ecules of solvation are disordered. In the crystal structure, there are O(water)—H⋯O(nitrate), C—H⋯O(water) and C—H⋯O(nitrate) hydrogen bonds.
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spelling pubmed-29608912010-12-30 (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate Navarro, Maribel Corona, Oscar A. González, Teresa Capparelli, Mario V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra­hedrally coordinated by a bidentate 2,2′-bipyridine ligand and two PPh(3) ligands. The Cu—N and Cu—P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra­hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring–ring C—C bond. The nitrate anion and the water and chloro­form mol­ecules of solvation are disordered. In the crystal structure, there are O(water)—H⋯O(nitrate), C—H⋯O(water) and C—H⋯O(nitrate) hydrogen bonds. International Union of Crystallography 2008-03-12 /pmc/articles/PMC2960891/ /pubmed/21201995 http://dx.doi.org/10.1107/S1600536808006260 Text en © Navarro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Navarro, Maribel
Corona, Oscar A.
González, Teresa
Capparelli, Mario V.
(2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title_full (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title_fullStr (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title_full_unstemmed (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title_short (2,2′-Bipyridine)bis­(triphenyl­phosphine)copper(I) nitrate chloro­form solvate hemihydrate
title_sort (2,2′-bipyridine)bis­(triphenyl­phosphine)copper(i) nitrate chloro­form solvate hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960891/
https://www.ncbi.nlm.nih.gov/pubmed/21201995
http://dx.doi.org/10.1107/S1600536808006260
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