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trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate

The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol­ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl­enediamine) lies on an inversion centre. The four N atoms of the en li...

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Detalles Bibliográficos
Autores principales: Moncol, Jan, Segľa, Peter, Mikloš, Dušan, Fischer, Andreas, Marian, Koman
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960896/
https://www.ncbi.nlm.nih.gov/pubmed/21201981
http://dx.doi.org/10.1107/S1600536808005400
Descripción
Sumario:The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol­ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl­enediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octa­hedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network.