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trans-Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate
The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water molecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethylenediamine) lies on an inversion centre. The four N atoms of the en li...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960896/ https://www.ncbi.nlm.nih.gov/pubmed/21201981 http://dx.doi.org/10.1107/S1600536808005400 |
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author | Moncol, Jan Segľa, Peter Mikloš, Dušan Fischer, Andreas Marian, Koman |
author_facet | Moncol, Jan Segľa, Peter Mikloš, Dušan Fischer, Andreas Marian, Koman |
author_sort | Moncol, Jan |
collection | PubMed |
description | The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water molecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethylenediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octahedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network. |
format | Text |
id | pubmed-2960896 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29608962010-12-30 trans-Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate Moncol, Jan Segľa, Peter Mikloš, Dušan Fischer, Andreas Marian, Koman Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water molecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethylenediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octahedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960896/ /pubmed/21201981 http://dx.doi.org/10.1107/S1600536808005400 Text en © Moncol et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Moncol, Jan Segľa, Peter Mikloš, Dušan Fischer, Andreas Marian, Koman trans-Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title |
trans-Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title_full |
trans-Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title_fullStr |
trans-Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title_full_unstemmed |
trans-Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title_short |
trans-Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis[3-(3-pyridyl)propionate] dihydrate |
title_sort | trans-diaquabis(ethylenediamine-κ(2)
n,n′)copper(ii) bis[3-(3-pyridyl)propionate] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960896/ https://www.ncbi.nlm.nih.gov/pubmed/21201981 http://dx.doi.org/10.1107/S1600536808005400 |
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