Cargando…

trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate

The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol­ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl­enediamine) lies on an inversion centre. The four N atoms of the en li...

Descripción completa

Detalles Bibliográficos
Autores principales: Moncol, Jan, Segľa, Peter, Mikloš, Dušan, Fischer, Andreas, Marian, Koman
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960896/
https://www.ncbi.nlm.nih.gov/pubmed/21201981
http://dx.doi.org/10.1107/S1600536808005400
_version_ 1782188851652984832
author Moncol, Jan
Segľa, Peter
Mikloš, Dušan
Fischer, Andreas
Marian, Koman
author_facet Moncol, Jan
Segľa, Peter
Mikloš, Dušan
Fischer, Andreas
Marian, Koman
author_sort Moncol, Jan
collection PubMed
description The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol­ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl­enediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octa­hedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network.
format Text
id pubmed-2960896
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29608962010-12-30 trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate Moncol, Jan Segľa, Peter Mikloš, Dušan Fischer, Andreas Marian, Koman Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol­ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl­enediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn–Teller octa­hedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds form a three-dimensional network. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960896/ /pubmed/21201981 http://dx.doi.org/10.1107/S1600536808005400 Text en © Moncol et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moncol, Jan
Segľa, Peter
Mikloš, Dušan
Fischer, Andreas
Marian, Koman
trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title_full trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title_fullStr trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title_full_unstemmed trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title_short trans-Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) bis[3-(3-pyrid­yl)propionate] dihydrate
title_sort trans-diaqua­bis(ethyl­enediamine-κ(2) n,n′)copper(ii) bis[3-(3-pyrid­yl)propionate] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960896/
https://www.ncbi.nlm.nih.gov/pubmed/21201981
http://dx.doi.org/10.1107/S1600536808005400
work_keys_str_mv AT moncoljan transdiaquabisethylenediaminek2nncopperiibis33pyridylpropionatedihydrate
AT seglapeter transdiaquabisethylenediaminek2nncopperiibis33pyridylpropionatedihydrate
AT miklosdusan transdiaquabisethylenediaminek2nncopperiibis33pyridylpropionatedihydrate
AT fischerandreas transdiaquabisethylenediaminek2nncopperiibis33pyridylpropionatedihydrate
AT mariankoman transdiaquabisethylenediaminek2nncopperiibis33pyridylpropionatedihydrate